Method for forming dielectric film to improve adhesion of...

Semiconductor device manufacturing: process – Coating of substrate containing semiconductor region or of... – Multiple layers

Reexamination Certificate

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C438S637000, C438S778000, C257SE21159, C257SE21160, C257SE21477, C257S774000, C257S760000

Reexamination Certificate

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07465676

ABSTRACT:
A semiconductor structure having improved adhesion between a low-k dielectric layer and the underlying layer and a method for forming the same are provided. The semiconductor substrate includes a dielectric layer over a semiconductor substrate, an adhesion layer on the dielectric layer wherein the adhesion layer comprises a transition sub-layer over an initial sub-layer, and wherein the transition sub-layer has a composition that gradually changes from a lower portion to an upper portion. A low-k dielectric layer is formed on the adhesion layer. Damascene openings are formed in the low-k dielectric layer. A top portion of the transition sub-layer has a composition substantially similar to a composition of the low-k dielectric layer. A bottom portion of the transition sub-layer has a composition substantially similar to a composition of the initial sub-layer.

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Yoon, S.W., et al., “Flipchip Bump Integrity with Copper/Ultra Low-k Dielectrics for Fine Pitch Flipchip Packaging,” 2004 Electronic Components and Technology Conference, IEEE, pp. 1636-1641.
Scherban, T., et al., “Interfacial Adhesion of Copper-Low k Interconnects,” IEEE, Interconnect Technology Conference, Jun. 4-6, 2001, pp. 257-259.

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