Method of forming metal silicide

Semiconductor device manufacturing: process – Coating with electrically or thermally conductive material – To form ohmic contact to semiconductive material

Reexamination Certificate

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C257SE21593

Reexamination Certificate

active

10772938

ABSTRACT:
A method of optimizing the formation of nickel silicide on regions of a MOSFET structure, has been developed. The method features formation of nickel silicide using an anneal procedure performed at a temperature below which nickel silicide instability and agglomeration occurs. A thin titanium interlayer is first formed on the MOSFET structure prior to nickel deposition, allowing an anneal procedure, performed after nickel deposition, to successfully form nickel silicide at a temperature of about 400° C. To obtain the desired conformality and thickness uniformity the thin titanium interlayer is formed via an atomic layer deposition procedure.

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Maa, Jer-Shen, et al, “Effect of Interlayer on Thermal Stability of Nickel Silicide”, J. Vac. Sci. Technol. A, vol. 19, No. 4, Jul./Aug. 2001, pp. 1595-1599.
Tan, W.L., et al., “Effect of a Titanium Cap in Reducing Interfacial Oxides in the Formation of Nickel Silicide”, Journal of Applied Physics, vol. 91, No. 5, Mar. 1, 2002, pp. 2901-2909.

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