Integration of high k gate dielectric

Semiconductor device manufacturing: process – Making field effect device having pair of active regions... – Having insulated gate

Reexamination Certificate

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C438S508000, C438S585000, C438S591000, C438S785000

Reexamination Certificate

active

07026219

ABSTRACT:
Methods are provided herein for forming electrode layers over high dielectric constant (“high k”) materials. In the illustrated embodiments, a high k gate dielectric, such as zirconium oxide, is protected from reduction during a subsequent deposition of silicon-containing gate electrode. In particular, a seed deposition phase includes conditions designed for minimizing hydrogen reduction of the gate dielectric, including low hydrogen content, low temperatures and/or low partial pressures of the silicon source gas. Conditions are preferably changed for higher deposition rates and deposition continues in a bulk phase. Desirably, though, hydrogen diffusion is still minimized by controlling the above-noted parameters. In one embodiment, high k dielectric reduction is minimized through omission of a hydrogen carrier gas. In another embodiment, higher order silanes aid in reducing hydrogen content for a given deposition rate.

REFERENCES:
patent: 3900597 (1975-08-01), Chruma et al.
patent: 4217374 (1980-08-01), Ovshinsky et al.
patent: 4237150 (1980-12-01), Wiesmann
patent: 4363828 (1982-12-01), Brodsky et al.
patent: 4379020 (1983-04-01), Glaeser et al.
patent: 4444812 (1984-04-01), Gutsche
patent: 4495218 (1985-01-01), Azuma et al.
patent: 4585671 (1986-04-01), Kitagawa et al.
patent: 4592933 (1986-06-01), Meyerson et al.
patent: 4634605 (1987-01-01), Wiesmann
patent: 4684542 (1987-08-01), Jasinski et al.
patent: 4745088 (1988-05-01), Inoue et al.
patent: 4871416 (1989-10-01), Fukuda
patent: 4963506 (1990-10-01), Liaw et al.
patent: 5037666 (1991-08-01), Mori
patent: 5080933 (1992-01-01), Grupen-Shemansky et al.
patent: 5082696 (1992-01-01), Sharp
patent: 5112773 (1992-05-01), Tuttle
patent: 5189504 (1993-02-01), Nakayama et al.
patent: 5198387 (1993-03-01), Tang
patent: 5227329 (1993-07-01), Kobayashi et al.
patent: 5242847 (1993-09-01), Ozturk et al.
patent: 5250452 (1993-10-01), Ozturk et al.
patent: 5324684 (1994-06-01), Kermani et al.
patent: 5389398 (1995-02-01), Suzuki et al.
patent: 5389570 (1995-02-01), Shiozawa
patent: 5453858 (1995-09-01), Yamazaki
patent: 5587344 (1996-12-01), Ishikawa
patent: 5607511 (1997-03-01), Meyerson
patent: 5607724 (1997-03-01), Beinglass et al.
patent: 5614257 (1997-03-01), Beinglass et al.
patent: 5648293 (1997-07-01), Hayama et al.
patent: 5656531 (1997-08-01), Thakur et al.
patent: 5695819 (1997-12-01), Beinglass et al.
patent: 5698771 (1997-12-01), Shields et al.
patent: 5700520 (1997-12-01), Beinglass et al.
patent: 5707744 (1998-01-01), King et al.
patent: 5786027 (1998-07-01), Rolfson
patent: 5789030 (1998-08-01), Rolfson
patent: 5837580 (1998-11-01), Thakur et al.
patent: 5863598 (1999-01-01), Venkatesan et al.
patent: 5874129 (1999-02-01), Beinglass et al.
patent: 5876797 (1999-03-01), Beinglass et al.
patent: 5879970 (1999-03-01), Shiota et al.
patent: 5885869 (1999-03-01), Turner et al.
patent: 5893949 (1999-04-01), King et al.
patent: 5930106 (1999-07-01), DeBoer et al.
patent: 5959326 (1999-09-01), Aiso et al.
patent: 5998289 (1999-12-01), Sagnes
patent: 6027705 (2000-02-01), Kitsuno et al.
patent: 6027975 (2000-02-01), Hergenrother et al.
patent: 6083810 (2000-07-01), Obeng et al.
patent: 6124626 (2000-09-01), Sandhu et al.
patent: 6159828 (2000-12-01), Ping et al.
patent: 6171662 (2001-01-01), Nakao
patent: 6180478 (2001-01-01), Lee et al.
patent: 6197669 (2001-03-01), Twu et al.
patent: 6197694 (2001-03-01), Beinglass
patent: 6228181 (2001-05-01), Yamamoto et al.
patent: 6281559 (2001-08-01), Yu et al.
patent: 6319782 (2001-11-01), Nakabayashi
patent: 6326311 (2001-12-01), Ueda et al.
patent: 6365479 (2002-04-01), U'Ren
patent: 6373112 (2002-04-01), Murthy et al.
patent: 6444512 (2002-09-01), Madhukar et al.
patent: 6455892 (2002-09-01), Okuno et al.
patent: 6613695 (2003-09-01), Pomarede et al.
patent: 2002/0098627 (2002-07-01), Pomarede et al.
patent: 0 368 651 (1990-05-01), None
patent: 54-4066 (1979-01-01), None
patent: 57209810 (1982-12-01), None
patent: 59078918 (1984-05-01), None
patent: 59078919 (1984-05-01), None
patent: 60043485 (1985-03-01), None
patent: 61153277 (1986-07-01), None
patent: 62076612 (1987-04-01), None
patent: 63003414 (1988-01-01), None
patent: 63003463 (1988-01-01), None
patent: 01217956 (1989-08-01), None
patent: 01268064 (1989-10-01), None
patent: 02155225 (1990-06-01), None
patent: 03091239 (1991-04-01), None
patent: 03185817 (1991-08-01), None
patent: 03187215 (1991-08-01), None
patent: 03292741 (1991-12-01), None
patent: 04323834 (1992-11-01), None
patent: 05021378 (1993-01-01), None
patent: 05062911 (1993-03-01), None
patent: 07249618 (1995-09-01), None
patent: 08242006 (1996-09-01), None
patent: 10163485 (1998-06-01), None
Ikoma et al., Growth of Si/3C-SIC/Si(100) hetrostructures by pulsed supersonic free jets, Applied Physics Letters, vol. 75, No. 25, pp. 3977-3979, Dec. 1999.
Angermeier et al., “Initial growth processes in the epitaxy of Ge with GeH4on oxidized Si substrates,”J. Electrochem. Soc.,vol. 144, No. 2, Feb. 1997, pp. 694-697.
Bensahel et al., “Industrial single wafer processing of in-situ doped polycrystalline Si and Si1-xGex,”Solid State Technology,Mar. 1998, pp. S5-S10.
Bloem, J., “High chemical vapour deposition rates of epitaxial silicon layers,”Journal of Crystal Growth,vol. 18, (1973), pp. 70-76.
Bodnar et al., “Single-wafer Si and SiGe processes for advanced ULSI technologies,”Thin Solid Films,vol. 294, (1997), pp. 11-14.
Rossi, Ronald C., “Low pressure chemical vapor deposition,”Handbook of Thin-Film Deposition Processes and Techniques,pp. 80-81.
Caymax, et al., “UHV-VLPCVD heteroepitaxial growth of thin SiGe-layers on Si-substrates: Influence of pressure on kinetics and on surface-morphology,”Solid State Phenomena,vol. 32-33, (1993), pp. 361-372.
Claassen et al., “Deposition of silicon from silane in a low-pressure hot-wall system,”Journal of Crystal Growth,vol. 57, No. 2, (1982), pp. 259-266.
Edwards et al., “Diffusion of Ge along grain boundaries during oxidation of polycrystalline silicon-germanium films,”Mat. Res. Soc. Symp. Proc.,vol. 319, (1994), pp. 183-188.
Edwards et al., “Dopant implantation and activation in polycrystalline-SiGe,”Mat. Res. Soc. Meeting—Sym. II,Spring 1994, 6 pages.
Eversteyn et al., “Influence of AsH3, and B2H6on the growth rate and resistivity of polycrystalline silicon films deposited from a SiH4-H2mixture,”Growth Rate and Resistivity of Si Films,vol. 120, No. 1, Jan. 1973, pp. 106-110.
Hernandez et al., “Evidence of interdiffusion effect in stacked polycrystalline SiGe/Si layers for CMOS gate application,”Mat. Res. Soc. Meeting,(19138), 6 pages.
Kamins et al., “Kinetics of silicon-germanium deposition by atmospheric-pressure chemical vapor deposition,”Appl. Phys. Lett.,vol. 59, No. 2, Jul. 8, 1991, pp. 178-180.
King et al., “A polycrystalline Si1-xGex-gate CMOS technology,”IEEE,vol. 253, (1990), pp. 10.4.1-10.4.4.
Li et al., “Rapid thermal chemical vapor deposition of polycrystalline silicon-germanium films on SiO2and their properties,”Mat. Res. Soc. Symp. Proc.,vol. 403, (1996), pp. 333-338.
Lin et al., “Effects of SiH4,GeH4,and B2H6on the nucleation and deposition of polycrystalline Si1-xGexfilms,”J. Electrochem. Soc.,vol. 141, No. 9, Sep. 1994, pp. 2559-2563.
Morosanu, C.E., “Thin films by chemical vapour deposition,”Thin Films Science and Technology,7, pp. 48.
Öztürk et al., “Rapid thermal chemical vapor deposition of germanium on silicon and silicon dioxide and new applications of Ge in ULSI technologies,”Journal of Electronic Materials,vol. 19, No. 10, (1990), pp. 1129-1134.
Skotnicki et al., “SiGe gate for highly performant 0.15/018βm CMOS technology,”ESSDERC,(1997), pp. 216.

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