Method for the stabilization of halogen-doped films through the

Semiconductor device manufacturing: process – Coating of substrate containing semiconductor region or of... – Multiple layers

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4272557, 427579, 438784, 438788, H01L 21316

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active

056610939

ABSTRACT:
A method and apparatus for depositing a halogen-doped oxide film having a low dielectric constant that is resistant to moisture absorption and outgassing of the halogen dopant, and that retains these qualities despite subsequent processing steps. The method begins by introducing process gases (including a halogen-containing source gas) into a processing chamber. A halogen-doped layer is then deposited. The combination of process gases is then changed and a sealing layer deposited which seals the dopant into the halogen-doped layer. The sealing layer may, for example, be a carbon-rich layer or an undoped layer. These steps are repeated until the film reaches a selected thickness.

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patent: 5429995 (1995-07-01), Nishiyama et al.
Musaka, Kasuyoki "Single Step Gap Filling Technology For Subhalf Micron Metal Spacings on Plasma Enhanced TEOS/O.sup.2 Chemical Vapor Deposition", Extended Abstracts Of The 1993 Int. Conf. On Solid State Devices and Materials, Mukuhari, 1993, pp. 510-512.

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