Method for forming dual high-k metal gate using photoresist...

Semiconductor device manufacturing: process – Making field effect device having pair of active regions... – Having insulated gate

Reexamination Certificate

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C438S703000, C216S041000, C216S049000, C430S322000, C430S329000

Reexamination Certificate

active

07915115

ABSTRACT:
Methods for forming a front-end-of-the-line (FEOL) dual high-k gate using a photoresist mask and structures thereof are disclosed. One embodiment of the disclosed method includes depositing a high-k dielectric film on a substrate of a FEOL CMOS structure followed by depositing a photoresist thereon; patterning the high-k dielectric according to the photoresist; and removing the photoresist thereafter. The removing of the photoresist includes using an organic solvent followed by removal of any residual photoresist including organic and/or carbon film. The removal of residual photoresist may include a degas process, alternatively known as a bake process. Alternatively, a nitrogen-hydrogen forming gas (i.e., a mixture of nitrogen and hydrogen) (N2/H2) or ammonia (NH3) may be used to remove the photoresist mask. With the use of the plasma nitrogen-hydrogen forming gas (N2/H2) or a plasma ammonia (NH3), no apparent organic residual is observed.

REFERENCES:
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patent: 6767698 (2004-07-01), Johnson
patent: 6805139 (2004-10-01), Savas et al.
patent: 6992011 (2006-01-01), Nemoto et al.
patent: 2007/0178637 (2007-08-01), Jung et al.
patent: 2008/0286697 (2008-11-01), Verhaverbeke et al.

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