Semiconductor device manufacturing: process – Making field effect device having pair of active regions... – Having insulated gate
Reexamination Certificate
1997-08-27
2001-06-19
Tsai, Jey (Department: 2812)
Semiconductor device manufacturing: process
Making field effect device having pair of active regions...
Having insulated gate
C438S254000
Reexamination Certificate
active
06248624
ABSTRACT:
FIELD OF THE INVENTION
The present invention generally relates to a method for forming dynamic random access memory (DRAM) stacked capacitor and more particularly, relates to a method for forming a fin-type DRAM stacked capacitor by depositing multiple layers of insulating materials in a single deposition process to enable the formation of a zig-zag configured bottom electrode of the capacitor in a subsequent wet etching process.
BACKGROUND OF THE INVENTION
In modern DRAM devices, small dimensions and high capacitance value per unit area of the capacitor are desirable characteristics for achieving a high charge storage capacity. A DRAM capacitor is normally formed by at least two layers of polysilicon films and one layer of a dielectric insulator. The DRAM devices have been named as dynamic because the cells can retain information only for a limited period of time and that they must be read and refreshed periodically. This is in contrast to a static random access memory (SRAM) cell which does not require periodic refresh signals in order to retain stored data.
A typical DRAM cell includes a field effect transistor and a storage capacitor. When DRAM cells were first developed, planar type storage capacitors which occupy large wafer surface areas were used. However, in modern memory devices where the dimensions of the device are continuously being miniaturized, methods for reducing the chip real estate required for a capacitor becomes more important. One of the methods encompasses a design of stacking a capacitor over the bit line on the surface of a silicon substrate in order to increase the specific capacitance of a storage capacitor. The stacked capacitor is formed by a layer of a dielectric material such as silicon dioxide or oxide-nitride-oxide sandwiched between two layers of polysilicon. The effective capacitance of the stacked capacitor cell is increased over that of a conventional planar cell due to its increased surface area.
Other techniques have also been tried in achieving higher capacitance on limited chip real estate. For instance, one method stores charges vertically in a trench which requires a deep trench formation resulting in significant processing difficulties. The stacked capacitor approach is therefore a well accepted and popular approach for achieving higher specific capacitance in a DRAM storage capacitor.
One of the possible configurations for a stacked capacitor is a fin-type stacked capacitor in which multiple number of fins generally formed of polysilicon is used as the bottom electrode for the capacitor. The increased surface areas on the fins contribute to the increased specific capacitance. A typical method for forming a fin-type stacked capacitor is shown in 
FIGS. 1A through 1G
.
Referring initially to 
FIG. 1A
, wherein a conventional semiconductor structure is shown. The semiconductor 
10
 consists of a silicon substrate 
12
 onto which a field oxide region 
14
 is first formed to isolate the field effect transistors 
16
. The field oxide 
14
 is typically formed by a LOCOS method during which silicon is thermally oxidized to form and to expand vertically into a silicon oxide region. The field effect transistor 
16
 is generally formed by first growing a thin oxide layer (not shown) on the silicon substrate as a gate oxide layer, and then forming a polysilicon gate electrode 
18
 on top of the gate oxide layer. The polysilicon layer which forms the gate electrode 
18
 is also used to form word line 
22
 over the field oxide 
14
 to provide interconnections between the transistors and the peripheral circuits on the chip. After lightly doped drain areas are formed in the substrate by an ion implantation method and sidewall spacers 
24
 are formed on the gate electrode 
18
, the transistor formation is completed by forming source/drain contact areas 
26
, 
28
 in the silicon substrate 
12
 adjacent to the gate electrode 
18
. A thick insulating layer 
32
 can be deposited over the gate electrode 
18
 and the word line 
22
 for electrical insulation. A silicon nitride etch stop layer 
34
 is then deposited over a planarized top surface of the insulating layer 
32
. The planarization process for the insulating layer 
32
 can be carried out advantageously by a chemical mechanical polishing technique.
In a conventional fin-type stacked capacitor process, as shown in 
FIG. 1B
, oxide layers 
36
, 
38
 and polysilicon layer 
40
 are deposited by a chemical vapor deposition technique on top of a silicon nitride etch step layer 
34
. The number of layers of polysilicon deposited is optional depending on the number offins ofthe stacked capacitor desired. On top of the final oxide layer 
38
, a photoresist layer 
42
 is then deposited and patterned. This is shown in FIG. 
1
C. Conventional photolithographic techniques and anisotropic plasma dry etching method are then used to form a contact opening 
46
. This is shown in FIG. 
1
D. The oxide layers 
32
, 
36
 and 
38
 and the polysilicon layer 
40
 are etched away to form the window opening such that a node contact 
48
 on the active area of the source/drain 
26
 is formed. The multiple layers of oxide and polysilicon can be etched in a reactive ion etching method by an etchant gas mixture containing fluorine or other etchant gas.
After the opening of the contact window 
46
 and the formation of the node contact 
48
 for the stacked capacitor to be built, a polysilicon layer 
52
 is blanket deposited over the oxide layer 
38
 and into the contact opening 
46
. The polysilicon layer 
52
 can be deposited by a low pressure to chemical vapor deposition (LPCVD) technique. The polysilicon layer 
52
 is then patterned by a photoresist layer (not shown) to define a bottom electrode 
56
. The anisotropic etching process for defining the bottom electrode 
56
 stops at the oxide layer 
36
. In the next processing step, a wet chemical etching method is used to remove the oxide layers 
36
 and 
38
 while maintaining the bottom electrode 
56
 intact and thus forming a freestanding fin-type polysilicon electrode 
56
 for the capacitor. This is shown in FIG. 
1
G. Onto the bottom electrode 
56
, a thin dielectric layer (not shown) and a thick polysilicon layer (not shown) are then deposited and patterned to form the capacitor dielectric and the capacitor top plate.
The conventional process for forming a fin-type stacked capacitor is a complicated process which requires multiple deposition steps for forming the multiple layers of oxide and polysilicon on top of the active device such that the fins can be formed. The process requires multiple deposition steps conducted in a series of processing chambers. It is a time consuming process which leads to low yield for the fabrication of fin-type stacked capacitors.
It is therefore an object of the present invention to provide a method for forming a fin-type DRAM stacked capacitor that does not have the drawbacks and shortcomings of a conventional capacitor forming process.
It is another object of the present invention to provide a method for forming a fin-type DRAM stacked capacitor by depositing multiple layers of different insulating materials in a single deposition process.
It is a further object of the present invention to provide a method for forming a fin-type DRAM stacked capacitor by depositing multiple layers of different insulating materials that have different etch rates in a single process chamber.
It is another further object of the present invention to provide a method for forming a fin-type DRAM stacked capacitor by first forming multiple layers of doped oxide and non-doped oxide insulating materials which have different etch rates.
It is still another object of the present invention to provide a method for forming a fin-type DRAM stacked capacitor by first depositing multiple layers of different oxide materials that have an etch rate ratio of greater than 3 when etched in a wet etch process.
It is yet another object of the present invention to provide a method for forming a fin-type DRAM stacked capacitor by first depositing multiple layers of different oxide m
Taiwan Semiconductor Manufacturing Company , Ltd.
Tsai Jey
Tung & Associates
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