Two step plasma etch method for forming self aligned contact

Semiconductor device manufacturing: process – Chemical etching – Vapor phase etching

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438723, 438724, 438743, 438744, 134 12, H01L 21302

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058175792

ABSTRACT:
A method for forming a via through a silicon oxide layer. There is first provided a substrate. There is then formed over the substrate a patterned silicon nitride layer which defines a contact beneath the patterned silicon nitride layer. There is then formed over the patterned silicon nitride layer a silicon oxide layer. There is then etched the silicon oxide layer through a first reactive ion etch (RIE) method employing a first etchant gas composition comprising a fluorocarbon etchant gas to form: (1) an etched silicon oxide layer which exposes the contact without substantially etching the patterned silicon nitride layer; and (2) a fluorocarbon polymer residue layer formed upon at least one of the etched silicon oxide layer and the patterned silicon nitride layer. Finally, there is stripped from the substrate the fluorocarbon polymer residue layer through a second reactive ion etch (RIE) method employing a second etchant gas composition comprising carbon tetrafluoride and oxygen. The method may also be employed in general for etching silicon oxide layers in the presence of silicon nitride layers. Similarly, the method may also in general be employed in removing fluorocarbon polymer residue layers from integrated circuit layers including but not limited to silicon oxide layers and silicon nitride layers.

REFERENCES:
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patent: 5554557 (1996-09-01), Koh
patent: 5595627 (1997-01-01), Inazawa et al.
"Dry Post-Etch Treatment Using SF.sub.6 Chemistry for 0.2 mu m Contract Hole."; Japanese Journal of Applied Physics Part 1; (Regular Paper & Short Notes); vol. 34; No. 9A; pp. 5001-5005; Sep. 1995; Seung et. al.
"Influence of Gas Chemistry And Ion Energy On Contact Resistance"; Japanese Journal of Appl. Phys., Part 1 (1996); 35(4B); pp. 2494-2500; Hashimi et. al, Apr. 1996.
Egitto et al. "Plasma Etching Organic Materials. I Polymiden 02-CF4", J. Vac. Sci Technology B3(3) May/Jun. 1985 pp. 893-904.

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