Semiconductor device and method for manufacturing the same

Semiconductor device manufacturing: process – Making field effect device having pair of active regions... – Having insulated gate

Reexamination Certificate

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C438S216000, C438S218000, C438S229000, C438S299000, C438S303000

Reexamination Certificate

active

06599792

ABSTRACT:

BACKGROUND OF THE INVENTION
1. Field of the Invention
The present invention relates to a semiconductor device and a method for manufacturing the same. More particularly, the present invention relates to a semiconductor device and a method for manufacturing the same, which is capable of reducing bubble defects.
2. Description of the Related Art
In general, a high-density plasma (HDP) oxide layer having a high step coverage property is used primarily as an insulating layer for filling gaps between patterns. Since a high temperature flow process is not required for the HDP oxide layer after deposition, the HDP oxide layer has been used as an interlayer dielectric (ILD) film.
FIG. 1
illustrates a sectional view of a semiconductor device in which a HDP oxide layer is used as an ILD film for filling a gap between gate electrodes.
Referring to
FIG. 1
, a gate insulating layer
12
, a doped polysilicon layer
14
, a metal silicide layer
16
, and a capping insulating layer
18
, are sequentially stacked on a semiconductor substrate
10
. Next, a portion of the capping insulating layer
18
, a portion of the metal silicide layer
16
, and a portion of the doped polysilicon layer
14
are patterned.
A spacer
20
is formed by a well-known method on both sidewalls of the patterned capping insulating layer
18
, the patterned metal silicide layer
16
, and the patterned doped polysilicon layer
14
, thereby forming a gate electrode structure
22
including the gate insulating layer
12
, the doped polysilicon layer
14
, the metal silicide layer
16
, the capping insulating layer
18
, and the spacer
20
.
A gate poly oxide (GPOX) layer
24
is deposited on the surface of the semiconductor substrate
10
on which the gate electrode structure
22
is formed. The GPOX layer
24
cures damage occurring in the patterning process for forming the gate electrode structure
22
by smoothing the edges of the gate electrode structure
22
and the surface of the semiconductor substrate
10
, thereby preventing electrostatic fields from being concentrated on the edges of the gate electrode structure
22
.
Next, impurity ions are implanted into the semiconductor substrate
10
at both sides of the gate electrode structure
22
, thereby forming a junction region
26
. An etch stopper
28
formed of silicon nitride (Si
3
N
4
) is deposited on the surface of the GPOX layer
24
. Next, a HDP oxide layer
30
is deposited as an interlayer dielectric ((ILD) film.
However, a conventional semiconductor device has the following problems. In general, lifting occurs at an interface between silicon oxide (SiO
2
) and a lower material of silicon oxide (SiO
2
), and at an interface between silicon oxide (SiO
2
) and silicon nitride (Si
3
N
4
), when the HDP oxide layer is deposited on a structure on which thin layers of silicon oxide (SiO
2
) and silicon nitride (Si
3
N
4
) are sequentially stacked. The interfacial lifting is referred to as bubble defects. When depositing the HDP oxide layer, the bubble defects are caused by a difference in stress between silicon oxide (SiO
2
) and silicon nitride (Si
3
N
4
), or by outgassed hydrogen ions.
The bubble defects occur in the above-mentioned semiconductor device. That is, the HDP oxide layer
30
is formed on the semiconductor substrate
10
including a stack comprised of the GPOX layer
24
formed of silicon oxide (SiO
2
) and the etch stopper
28
formed of silicon nitride (Si
3
N
4
), and thus, the bubble defects occur.
Due to the bubble defects occurring in the semiconductor device, the adhesive strength of the interfaces is lowered, particles occur in the lift, and electrical properties of the semiconductor device are degraded.
In order to prevent the bubble defects, a method for relatively increasing the thickness of either the GPOX layer
24
or the etch stopper
28
has been suggested. However, in this case, the spacing between the gate electrode structures
22
is reduced, and thus a gap fill margin of the HDP layer
30
is reduced. Accordingly, the stress between the GPOX layer
24
and the etch stopper
28
is reduced.
SUMMARY OF THE INVENTION
In an effort to solve the above problem, it is a first feature of an embodiment of the present invention to provide a semiconductor device capable of reducing bubble defects in a gate electrode structure without reducing a gap fill margin of an interlayer dielectric (ILD) film.
It is a second feature of an embodiment of the present invention to provide a method for manufacturing a semiconductor device capable of reducing bubble defects.
Accordingly, to provide the first feature, according to one aspect of the present invention, there is provided a method for manufacturing a semiconductor device. In the method, a gate electrode structure is formed on a surface of a semiconductor substrate. A gate poly oxide (GPOX) layer is deposited on a surface of the gate electrode structure and on the semiconductor substrate. The surface of the semiconductor substrate is cleaned to remove any residue and the GPOX layer. An etch stopper is formed on the surface of the gate electrode structure and on the semiconductor substrate. A high-density plasma (HDP) oxide layer is deposited on the etch stopper.
The semiconductor substrate may be cleaned using a solution in which a buffer oxide etchant (BOE) (HF+NH
4
F) solution is mixed with a standard cleaning
1
(SC
1
) (NH
4
OH+H
2
O
2
+H
2
O) solution. Pre-processing the surface of the semiconductor substrate using a high temperature sulfuric acid solution may be further performed after forming the gate electrode structure and before cleaning the surface of the semiconductor substrate.
A preferred formation of the gate electrode structure will now be described. In the preferred formation, a gate insulating layer, a conductive layer, and a capping insulating layer are sequentially formed on the semiconductor substrate. The capping insulating layer and the conductive layer are patterned. A spacer is formed on both sidewalls of the capping insulating layer and the conductive layer. In this case, after patterning the capping insulating layer and the conductive layer and before forming the spacer on both sidewalls of the capping insulating layer and the conductive layer, low concentration impurity ions are implanted into the semiconductor substrate at both sides of the patterned capping insulating layer and the patterned conductive layer. In addition, after forming the spacer, high concentration impurity ions are implanted into the semiconductor substrate at both sides of the spacer.
Further, after patterning the capping insulating layer and the conductive layer and before implanting low concentration impurity ions into the semiconductor substrate, an intermediate GPOX layer is additionally formed on the surface of the semiconductor substrate and on the surface of the conductive layer. The intermediate GPOX layer additionally formed is formed by a thermal oxidation method.
To provide the first feature, according to another aspect of the present invention, there is provided a method for manufacturing a semiconductor device.
A gate electrode structure is formed on a surface of a semiconductor substrate. An etch stopper is formed on the surface of the gate electrode structure and on the semiconductor substrate. A high-density plasma (HDP) oxide layer is deposited on the etch stopper.
After forming the gate electrode structure and before forming the etch stopper, the surface of the semiconductor substrate may be cleaned.
To provide the second feature, there is provided a semiconductor device. The semiconductor device includes a semiconductor substrate, a gate electrode structure formed on the semiconductor substrate, an etch stopper covering the semiconductor substrate and a surface of the gate electrode structure, and a high-density plasma (HDP) oxide layer formed on the etch stopper.


REFERENCES:
patent: 6156636 (2000-12-01), Yeom et al.
patent: 6218715 (2001-04-01), Kim et al.
patent: 6323103 (2001-11-01), Rengarajan et al.
patent: 6420250 (2002-07-01), Cho et al.
patent: 64653

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