Semiconductor device manufacturing: process – Coating with electrically or thermally conductive material – To form ohmic contact to semiconductive material
Reexamination Certificate
2007-05-01
2007-05-01
Fourson, George (Department: 2823)
Semiconductor device manufacturing: process
Coating with electrically or thermally conductive material
To form ohmic contact to semiconductive material
C438S653000, C257SE21584
Reexamination Certificate
active
10709865
ABSTRACT:
Methods of depositing a tantalum-nitride (TaN) diffusion barrier region on low-k materials. The methods include forming a protective layer on the low-k material substrate by performing plasma-enhanced atomic layer deposition (PE-ALD) from tantalum-based precursor and a nitrogen plasma in a chamber. The protective layer has a nitrogen content greater than its tantalum content. A substantially stoichiometric tantalum-nitride layer is then formed by performing PE-ALD from the tantalum-based precursor and a plasma including hydrogen and nitrogen. The invention also includes the tantalum-nitride diffusion barrier region so formed. In one embodiment, the metal precursor includes tantalum penta-chloride (TaCl5). The invention generates a sharp interface between low-k materials and liner materials.
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Rossnagel, S.M., et al., “Plasma-Enhanced Atomic Layer Deposition of Ta and Ti for Interconnect Diffusion Barriers”, J Vac Sci Technol B 18(4), Jul./Aug. 2000, pp. 2016-2020.
Dunn Derren N.
Kim Hyung-jun
Rossnagel Stephen M.
Seo Soon-Cheon
Fourson George
Hoffman Warnick & D'Alessandro LLC
Jaklitsch Lisa U.
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