Method of manufacturing DRAM capacitor

Semiconductor device manufacturing: process – Making field effect device having pair of active regions... – Having insulated gate

Reexamination Certificate

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C438S255000, C438S396000, C438S398000, C438S947000

Reexamination Certificate

active

06391708

ABSTRACT:

CROSS-REFERENCE TO RELATED APPLICATION
This application claims the priority benefit of Taiwan application serial no. 87112531, filed Jul. 30, 1998, the full disclosure of which is incorporated herein by reference.
BACKGROUND OF THE INVENTION
1. Field of Invention
The present invention relates to a method of manufacturing a dynamic random access memory (DRAM) capacitor. More particularly, the present invention relates to a method that utilizes a porous oxide layer in the process of forming a DRAM capacitor.
2. Description of Related Art
At present, ultra-large scale integration (ULSI) semiconductor fabrication techniques have considerably increased circuit density on a silicon chip. However, to achieve high circuit density, the dimensions of each device must be downsized correspondingly and devices must be packed closer together. Since the structure of DRAM is suitable for high-density packing, DRAMs are extensively used in the electronic industry for data storage. Each DRAM comprises a large number of memory cells, and data is stored according to the charging state in the capacitor of a memory cell. The data is accessed through memory peripheral address and read/write circuits around the silicon chip. Furthermore, each DRAM cell includes a field effect transistor (FET) and a capacitor so that a single bit of information is represented by each cell. The capacitor of a DRAM cell is a critical element of the unit. The larger the amount of electric charges that can be stored in a DRAM capacitor, the smaller the effect of noise on the read out data is. For example, soft errors due to a - particles can be greatly reduced.
As the number of transistors on a DRAM chip continues to increase, the size of each transistor must be reduced. Consequently, the amount of charges within each DRAM capacitor must be small enough to produce an acceptable signal-to-noise level. However, if the amount of charges stored in a capacitor is further lowered, the number of refresh cycles has to be increased. Therefore, in order to provide a larger capacitance without having to occupy a greater surface area on a silicon chip, more efficient capacitor structures are required.
In general, trench-type and stacked-type capacitors are the two most commonly used capacitor structures. Among the two, trench-type capacitors are less frequently used because they are more difficult to fabricate. A stacked capacitor has a structure that extends vertically up from a substrate surface, and hence is capable of providing greater capacitor area without having to deal with too many manufacturing problems. There are a number of variations in the design of a stacked capacitor.
FIG. 1
is a cross-sectional view of a conventional, cylindrical-type, stacked capacitor, and
FIG. 2
is a cross-sectional view of a conventional, fin-type stacked capacitor. Both cylindrical and fin-type capacitors are capable of increasing surface area of the capacitor so that more electric charges can be stored.
The cylindrical-shaped capacitor shown in
FIG. 1
is built upon a semiconductor substrate
10
. The capacitor has a source/drain region
12
in the substrate
10
and an insulating layer
14
above the substrate
10
. Within the insulating layer
14
, there is a storage node opening
15
. Furthermore, there is a cylindrical-shaped capacitor structure
19
in and on top of the storage node opening
15
. The cylindrical-shaped capacitor structure
19
further includes a lower electrode
16
, a dielectric layer
17
and an upper electrode
18
.
The fin-shaped capacitor as shown in
FIG. 2
is built upon a semiconductor substrate
20
. The capacitor has a source/drain region
22
in the substrate
20
and an insulating layer
24
above the substrate
20
. Within the insulating layer
24
, there is a storage node opening
25
. Furthermore, there is a fin-shaped capacitor structure
29
in and on top of the storage node opening
25
. The fin-shaped capacitor structure
29
further includes a lower electrode
26
, a dielectric layer
27
and an upper electrode
28
.
Although the above stacked capacitors can increase the surface area of a capacitor somewhat, larger surface area and more efficient methods of fabrication are always in demand to bring down the cost.
In light of the foregoing, there is still a need to improve the method of manufacturing DRAM capacitor.
SUMMARY OF THE INVENTION
Accordingly, the present invention provides a method that employs plasma-etching techniques in combination with a porous oxide layer mask for manufacturing a DRAM capacitor whose lower electrode has a larger surface area.
To achieve these and other advantages and in accordance with the purpose of the invention, as embodied and broadly described herein, the invention provides a method of manufacturing a DRAM capacitor. The method includes the steps of providing a semiconductor substrate having a source/drain region thereon, and then forming an insulating layer over the substrate. Next, a storage node opening that exposes the source/drain region is formed in the insulating layer, and then a first conductive layer is formed above the storage node opening and the insulating layer. Thereafter, porous insulating material is deposited over the first conductive layer. The porous material includes porous oxide, sold under the trademark NanoPorous Silicon™ or a Xerogel Sol-Gel# for example. Subsequently, the porous oxide layer is used as a mask for carrying out a plasma-etching operation so that a portion of the first conductive layer is etched away. Therefore, a multiple of long and narrow crevices is etched out forming a fork-shaped first conductive layer structure. The fork-shaped first conductive layer serves as the lower electrode of a capacitor. Subsequently, the porous oxide layer is removed, and then a dielectric layer is formed over the fork-shaped structure. Finally, a second conductive layer that serves as the upper electrode of a capacitor is formed over the dielectric layer.
It is to be understood that both the foregoing general description and the following detailed description are exemplary, and are intended to provide further explanation of the invention as claimed.


REFERENCES:
patent: 5158905 (1992-10-01), Ahn
patent: 5164881 (1992-11-01), Ahn
patent: 5227322 (1993-07-01), Ko et al.
patent: 5466627 (1995-11-01), Lur et al.
patent: 5616511 (1997-04-01), Hirota
patent: 5650351 (1997-07-01), Wu
patent: 5670405 (1997-09-01), Tseng
patent: 5670406 (1997-09-01), Tseng
patent: 5681774 (1997-10-01), Tseng
patent: 5976444 (1999-11-01), Pearson et al.
patent: 6150217 (2000-11-01), Chang et al.
Wolf et al., “Dry Etching For VLSI Fabrication”, Silicon Processing For the VLSI Era, vol. 1—Process Technology, pp. 540-541 (1986).

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