Method of etching contacts with reduced oxide stress

Semiconductor device manufacturing: process – Making field effect device having pair of active regions... – Having insulated gate

Reexamination Certificate

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C438S296000, C438S437000, C438S788000

Reexamination Certificate

active

06333218

ABSTRACT:

FIELD OF THE INVENTION
The present invention relates generally to semiconductor devices and manufacturing processes, and particularly to methods for precisely controlling an etch process to form local interconnect lines.
BACKGROUND OF THE INVENTION
Current demands for high density and performance associated with ultra large scale integration (ULSI) requires submicron features of about 0.25 microns and under, increased transistor and circuit speeds and improved reliability. Such demands for increased density, performance and reliability require formation of device features with high precision and uniformity.
As device features are increasingly miniaturized to increase the integration density, the need for effective isolation between individual devices becomes more critical. For the purpose of effective isolation between electrical devices, various isolation technologies have been introduced. An earlier method known as LOCOS (Local Oxidation of Silicon) was developed for MOSFET devices to prevent the establishment of parasitic channel between adjacent device. The LOCOS isolation technique involves the formation of an oxide bulk in the non-active area on the semiconductor substrate. The well-known drawbacks associated with LOCOS isolation are the formation of the so-called “bird's beak” oxide configuration and the associated encroachment of the field oxide beneath the oxidation mask.
As device dimensions reached submicron size, conventional LOCOS isolation technologies attained the limit of their effectiveness, and alternative isolation techniques were developed to increase the device density. One such isolation technology developed involves a process of creating trench structure during the integrated circuit fabrication. The utilization of trench structures to form isolation areas accomplished several major improvements such as prevention of latch-up and effective isolation of n-well regions from p-doped substrate in CMOS devices.
Typically, trench isolation involves etching a narrow, deep trench or groove in a silicon substrate and then filling the trench with a hard filling material such as silicon oxide. A problem with the use of hard materials is that they may cause dislocations and other defects in the silicon substrate during the subsequent thermal processes due to the differences in rates of thermal expansion between the filler material and the silicon substrate. For example, the trenches typically have contacts between a silicon substrate and silicon dioxide layers formed thereon. Because of the differing thermal coefficients of expansion of silicon and silicon dioxide, a stress problem from the mismatch occurs at the interface between the layers of silicon and silicon dioxide. This stress tends to cause undesirable damage in the silicon substrate near the trefich. Particularly, top edges of the trenches are susceptible to the generation of significant stress defects.
With this in mind,
FIG. 1
depicts a cross-section of a portion of a prior art semiconductor device, which comprises a trench liner
12
formed on a silicon substrate
10
. Conventionally, trench liner
12
is silicon dioxide formed by a conventional thermal oxidation process, i.e., at an oxidation temperature of 1050° C. or less. During the thermal oxidation process to form silicon dioxide trench liner
12
, oxidation stress is formed in interface region
14
within substrate
10
due to the different thermal expansion coefficients of silicon and silicon dioxide.
A trench isolation region
16
has been formed on trench liner
12
by filling the trench with oxide material, typically TEOS. The portion further includes a gate region
18
that is part of a field effect transistor having an active region
20
, either a source or drain region, formed adjacent to trench isolation region
16
within substrate
10
. Conductive silicide regions
22
have been formed on the top surface of active region
20
and gate region
18
. A dielectric material, such as silicon dioxide derived from tetraethyl orthosilicate (TEOS) has been deposited over the substrate
10
to form an interlayer dielectric
24
, and then the surface of interlayer dielectric
24
has been planarized. A local interconnection opening
26
has been formed by conventional etching processes, extending through dielectric layer
24
to silicide regions
22
. Barrier layer
28
is then formed on the inner surface of local interconnect opening
22
.
During the dielectric etching process to form local interconnection opening
22
, it is desirable to stop the etching process at the silicide regions
22
formed on active region
20
. However, it is often difficult to precisely stop the etching process at the silicide region
22
. One reason is that the thermal oxidation process to form trench liner
12
causes undesirable stress defects in an interface region
14
between substrate
10
and trench liner
12
, especially near the top edges of the trench isolation region
16
. The stress defects in the interface region
14
make it difficult to precisely stop etching interlayer dielectric
24
at silicide region
22
. This often causes local interconnect openings to extend through silicide region
22
to substrate
10
, thereby-forming a dip
29
in the top surface of interface region
14
. Upon filling local interconnect opening
26
with a conductive material to form a local interconnect line, a conductive path is undesirably created between the local interconnect line and substrate
10
through dip
29
, thereby resulting in an intolerable amount of leakage current which decreases circuit performance, and in extreme circumstances, may cause failure of the circuit.
Thus, there is a need for a method that substantially reduces the stress defect at the top surface of an interface region between a substrate and a trench liner to prevent undesirable formation of a conductive path between the local interconnect line and the substrate.
SUMMARY OF THE INVENTION
These and other needs are met by the present invention which provides an improved method of forming trench isolation regions on semiconductor substrates. The method comprises the steps of forming a trench of a trench isolation region on a portion of a top surface of a semiconductor substrate, the trench having an inner surface, and depositing a trench liner on the inner surface of the trench by high density plasma (HDP) deposition.
The deposition of a trench liner, such as high temperature HDP oxide, on the inner surface of the trench by HDP deposition, produces a trench liner with low compressive stress since the process is stress neutral. This substantially reduces stress defects in the interface region between the silicon substrate and the liner formed thereon. Spiking of the junction produced during etching at the substrate-liner interface is thereby reduced.
The earlier stated needs are met by another embodiment of the present invention which provides a method of manufacturing a semiconductor device, comprising the steps of forming a trench of a trench isolation region in a portion of a top surface of a semiconductor substrate and depositing oxide as a trench liner in the trench using high density plasma (HDP) deposition. The trench is filled with an insulating material to form a trench isolation region. An active region is formed in the top surface adjacent to the oxide liner and a dielectric layer is deposited over the top surface, active region and trench isolation region. The dielectric layer is then etched to form a local interconnection opening exposing the active region. The trench liner deposited by HDP deposition substantially prevents the local interconnection opening from reaching the substrate between the active region and the trench isolation region. Following the etching, the local interconnection opening is filled with a conductive material.
The local interconnect formed by the methods of the present invention does not have an undesirable conductive path between the local interconnect line and the substrate through the trench liner. This is due to the substantially reduced stress de

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