Method and structure for isolating integrated circuit...

Semiconductor device manufacturing: process – Formation of electrically isolated lateral semiconductive... – Recessed oxide by localized oxidation

Reexamination Certificate

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C438S297000, C438S424000, C438S425000

Reexamination Certificate

active

06399462

ABSTRACT:

FIELD OF THE INVENTION
The present invention relates generally to a method of forming local oxidation isolation structures in semiconductor and/or integrated circuit devices and, more particularly, relates to a method of forming such isolation structures that reduces stress-related defects and that results in a reduced or negligible bird's beak.
BACKGROUND
All integrated circuits (ICs) have electric circuits which include a number of isolated devices, e.g., transistors, interconnected through one or more conducting paths. Thus, to fabricate ICs, the individual devices must be created in a silicon substrate in such a way that they are electrically isolated from one another. Isolation of the individual devices ensures that the state (e.g., on or off) and conductance of the individual devices are independently controlled. Without proper isolation, leakage currents may occur, causing power dissipation, noise margin degradation and/or voltage shifts on dynamic nodes. In CMOS circuits, leakage currents may lead to device latch up, which can damage the integrated circuit. Further, without proper isolation, cross-talk between devices may occur, thereby disturbing the logic state of a gate which is made up of a number of the individual devices.
Integrated circuit designers face other challenges that may conflict with the desire for proper isolation. For example, it is commercially important to make the spacing between individual components or devices as small as possible to enable increases in device density (e.g., number of devices per unit area). Furthermore, there is a strong desire in the art to ensure that the fabrication processes which are used to produce the isolation structures are simple to implement and control while, at the same time, these processes should not adversely impact the characteristics of active areas of the semiconductor die which will form the integrated circuit.
To meet these and other challenges in manufacturing semiconductor devices, Local Oxidation of Silicon (LOCOS) has become a widely used processing step in forming lateral isolation structures between devices (e.g., transistors) on a semiconductor die. Indeed, the LOCOS process has become the “work horse” isolation technology for MOS devices down to about 0.5 &mgr;m geometries. LOCOS processes are popular, in part, because they produce a fairly planar surface which is highly desirable for resolving and patterning dense features on a semiconductor die.
FIG. 1
illustrates a semiconductor die
10
at one stage of a conventional LOCOS process. A thin layer of a pad oxide of approximately 10 to 50 nm thickness is formed on the surface of a silicon substrate
12
. Next, a thicker layer of silicon nitride
16
is deposited on the pad oxide layer
14
. The silicon nitride layer
16
may be approximately 100 to 150 nm thick and may be deposited using conventional chemical vapor deposition (CVD) techniques.
In the resulting structure, the pad oxide layer
14
is used to cushion the transition of stresses between the silicon substrate
12
and the nitride layer
16
. Such stresses may occur in the nitride layer
16
due to various effects, including: (1) a mismatch between the thermal co-efficient of expansion of the nitride layer
16
and the silicon substrate
12
; and (2) a tendency of the growing field oxide (see below) to lift the edges of the nitride layer
16
. Such stresses may cause the nitride layer
16
to crack as the field oxide layer is grown, thus defeating the purpose of the nitride layer
16
as an oxidation barrier.
Stresses may also be transmitted from the nitride layer
16
to the silicon substrate
12
. These stresses may produce defects in the silicon crystal. In general, the thicker the pad oxide layer
14
, the fewer the defects in both the nitride layer
16
and the silicon substrate
12
during the field oxide layer growth. However, a thick pad oxide layer
14
may render the nitride layer
16
less effective as an oxidation mask by allowing lateral oxidation to take place. Consequently, the thinnest pad oxide layer
14
that effectively relieves stress is generally employed.
After the nitride layer
16
is deposited, it may be patterned, for example by using conventional photolithography techniques wherein in a photoresist layer (not shown) is spun on and exposed though a mask. As shown in
FIG. 2
, the nitride layer
16
and pad oxide layer
14
may then be etched to expose a top surface of the silicon substrate
12
in a region
18
that will become an isolation structure. In other words, the nitride layer
16
and pad oxide layer
14
are patterned so that after the etch they remain only over what will become the active regions in the silicon substrate
12
.
With the region
18
still exposed, the silicon substrate
12
is oxidized to form a field oxide region
20
of desired thickness. The result is shown in
FIG. 3
where a field oxide region
20
has been grown over silicon substrate
12
. Even though this oxide grows mainly in areas where the silicon nitride layer
16
is absent, the oxide generally grows by diffusion, resulting in both vertical growth in the isolation region and lateral growth under the nitride and pad oxide layers,
16
and
14
. This lateral growth of the field oxide results in a so-called bird's beak, because the shape of the oxide grown under the nitride layer resembles that of a bird's beak. Because it is the beak-to-beak distance “b” (see
FIG. 4
) over the silicon substrate
12
which will define the active transistor area, the smaller the bird's beak, the closer devices (e.g., transistors) can be packed onto a given substrate. In other words, bird's beak encroachment leads to active areas that are narrower than originally patterned. What is desired is as small a bird's beak as possible.
Because of the bird's beak phenomenon, conventional LOCOS processes are generally considered most appropriate for technologies having transistor gate widths of approximately 0.5 &mgr;m, or greater. That is, it has been recognized in the literature (see, e.g., Stanley Wolf, Silicon Processing for the VLSI Era, Vol. 3, Ch. 6, p. 367) that conventional LOCOS technologies are not suitable for device geometries of less than 0.5 &mgr;m. To overcome this barrier, some variations of conventional LOCOS have been proposed which attempt to minimize the bird's beak effect. For example, techniques such as sidewall masked isolation and poly-buffered LOCOS have been developed to reduce the effect of bird's beak. In general, however, these techniques typically require additional processing steps, therefore making the processes more complex and more costly. Another drawback of conventional LOCOS is that it is susceptible to “defects” caused by the high stresses generated in the narrow active areas, underneath the nitride layer, during the field oxidation. These defects can degrade the gate oxide quality and transistor performance. The defect generation gets enhanced as the geometries shrink and the bird's beak encroachment becomes more significant. What is desired, therefore, is a means of forming an isolation structure in a semiconductor substrate having a reduced bird's beak that does not have the drawbacks and shortcomings of conventional methods and/or known variations thereof.
SUMMARY OF INVENTION
The present invention concerns a method of forming an isolation region in a semiconductor wafer or die. The semiconductor die generally includes a semiconductor (preferably silicon) substrate, an oxide layer thereon and a nitride layer on the oxide layer. The nitride layer is patterned to expose an isolation region, then subsequently etched so that a region of the nitride layer adjacent to the isolation region has a nearly vertical sidewall. The etch step may be continued or one or more separate etching steps may be conducted to etch the exposed oxide layer (i.e., in the isolation region) and a region having a sloped sidewall with respect to the nearly vertical sidewall of the nitride layer is formed in the silicon substrate. A field o

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