Evaporation of Y-Si-O films for medium-k dielectrics

Semiconductor device manufacturing: process – Making field effect device having pair of active regions... – Having insulated gate

Reexamination Certificate

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C438S778000, C438S787000

Reexamination Certificate

active

06812100

ABSTRACT:

FIELD OF THE INVENTION
The invention relates to semiconductor devices and device fabrication. Specifically, the invention relates to gate oxide layers of transistor devices and their method of fabrication.
BACKGROUND OF THE INVENTION
In the semiconductor device industry, particularly in the fabrication of transistors, there is continuous pressure to reduce the size of devices such as transistors. The ultimate goal is to fabricate increasingly smaller and more reliable integrated circuits (ICs) for use in products such as processor chips, mobile telephones, or memory devices such as DRAMs. The smaller devices are frequently powered by batteries, where there is also pressure to reduce the size of the batteries, and to extend the time between battery charges. This forces the industry to not only design smaller transistors, but to design them to operate reliably with lower power supplies.
A common configuration of a transistor is shown in FIG.
1
. While the following discussion uses
FIG. 1
to illustrate a transistor from the prior art, one skilled in the art will recognize that the present invention could be incorporated into the transistor shown in
FIG. 1
to form a novel transistor according to the invention. The transistor
100
is fabricated in a substrate
110
that is typically silicon, but could be fabricated from other semiconductor materials as well. The transistor
100
has a first source/drain region
120
and a second source/drain region
130
. A body region
132
is located between the first source/drain region and the second source/drain region, the body region
132
defining a channel of the transistor with a channel length
134
. A gate dielectric, or gate oxide
140
is located on the body region
132
with a gate
150
located over the gate oxide. Although the gate dielectric can be formed from materials other than oxides, the gate dielectric is typically an oxide, and is commonly referred to as a gate oxide. The gate may be fabricated from polycrystalline silicon (polysilicon) or other conducting materials such as metal may be used.
In fabricating transistors to be smaller in size and reliably operating on lower power supplies, one important design criteria is the gate oxide
140
. A gate oxide
140
, when operating in a transistor, has both a physical gate oxide thickness and an equivalent oxide thickness (EOT). The equivalent oxide thickness quantifies the electrical properties, such as capacitance, of a gate oxide
140
in terms of a representative physical thickness. EOT is defined as the thickness of a theoretical SiO
2
layer that describes the actual electrical operating characteristics of the gate oxide
140
in the transistor
100
. For example, in traditional SiO
2
gate oxides, a physical oxide thickness may be 5.0 nm, but due to undesirable electrical effects such as gate depletion, the EOT may be 6.0 nm. A gate oxide other than SiO
2
may also be described electrically in terms of an EOT. In this case, the theoretical oxide referred to in the EOT number is an equivalent SiO
2
oxide layer. For example, SiO
2
has a dielectric constant of approximately 4. An alternate oxide with a dielectric constant of 20 and a physical thickness of 100 nm would have an EOT of approximately 20 nm=(100*(4/20)), which represents a theoretical SiO
2
gate oxide.
Lower transistor operating voltages and smaller transistors require thinner equivalent oxide thicknesses (EOTs). A problem with the increasing pressure of smaller transistors and lower operating voltages is that gate oxides fabricated from SiO
2
are at their limit with regards to physical thickness and EOT. Attempts to fabricate SiO
2
gate oxides thinner than today's physical thicknesses show that these gate oxides no longer have acceptable electrical properties. As a result, the EOT of a SiO
2
gate oxide
140
can no longer be reduced by merely reducing the physical gate oxide thickness.
Attempts to solve this problem have led to interest in gate oxides made from oxide materials other than SiO
2
. Certain alternate oxides have a higher dielectric constant (k), which allows the physical thickness of a gate oxide
140
to be the same as existing SiO
2
limits or thicker, but provides an EOT that is thinner than current SiO
2
limits.
A problem that arises in forming an alternate oxide layer on the body region of a transistor is the process in which the alternate oxide is formed on the body region. Recent studies show that the surface roughness of the body region has a large effect on the electrical properties of the gate oxide, and the resulting operating characteristics of the transistor. The leakage current through a physical 1.0 nm gate oxide increases by a factor of 10 for every 0.1 increase in the root-mean-square (RMS) roughness. In forming an alternate oxide layer on the body region of a transistor, a thin layer of the alternate material to be oxidized (typically a metal) must first be deposited on the body region. Current processes for depositing a metal or other alternate layer on the body region of a transistor are unacceptable due to their effect on the surface roughness of the body region.
FIG. 2A
shows a surface
210
of a body region
200
of a transistor. The surface
210
in
FIG. 2A
has a high degree of smoothness, with a surface variation
220
.
FIG. 2B
shows the body region
200
during a conventional sputtering deposition process stage. During sputtering, particles
230
of the material to be deposited bombard the surface
210
at a high energy. When a particle
230
hits the surface
210
, some particles adhere as shown by particle
235
, and other particles cause damage as shown by pit
240
. High energy impacts can throw off body region particles
215
to create the pits
240
. A resulting layer
250
as deposited by sputtering is shown in FIG.
2
C. The deposited layer/body region interface
255
is shown following a rough contour created by the sputtering damage. The surface of the deposited layer
260
also shows a rough contour due to the rough interface
255
.
In a typical process of forming an alternate material gate oxide, the deposited layer
250
is oxidized to convert the layer
250
to an oxide material. Existing oxidation processes do not, however, repair the surface damage created by existing deposition methods such as sputtering. As described above, surface roughness has a large influence on the electrical properties of the gate oxide and the resulting transistor.
What is needed is an alternate material gate oxide that is more reliable at existing EOTs than current gate oxides. What is also needed is an alternate material gate oxide with an EOT thinner than conventional SiO
2
. What is also needed is an alternative material gate oxide with a smooth interface between the gate oxide and the body region. Because existing methods of deposition are not capable of providing a smooth interface with an alternate material gate oxide, what is further needed is a method of forming an alternate material gate oxide that maintains a smooth interface.
Additionally, at higher process temperatures, any of several materials used to fabricate the transistor, such as silicon, can react with other materials such as metals or oxygen to form unwanted silicides or oxides. At high process temperatures, materials such as dopants can also migrate to unwanted areas, changing the desired structure or composition profile that is desired. What is needed is a lower temperature process of forming gate oxides that prevents migration and the formation of unwanted byproduct materials.
SUMMARY OF THE INVENTION
A method of forming a gate oxide on a surface such as a transistor body region is shown. The method includes evaporation depositing a metal on the body region and additionally evaporation depositing a metal oxide on the body region. In one embodiment of the invention, the metal includes yttrium, and the metal oxide includes silicon dioxide (SiO
2
). In one embodiment, the metal and the metal oxide are evaporated concurrently in a single processing step.
In addition to the novel proc

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