Electroplated copper interconnection structure, process for...

Active solid-state devices (e.g. – transistors – solid-state diode – Combined with electrical contact or lead – Of specified material other than unalloyed aluminum

Reexamination Certificate

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C257S751000, C257S752000, C257S753000, C257SE21579, C257SE21584, C257SE21585

Reexamination Certificate

active

10810719

ABSTRACT:
Interconnect structures with copper conductors being at least substantially free of internal seams or voids are obtained employing an electroplating copper bath containing dissolved cupric salt wherein the concentration of the salt is at least about 0.4 molar and up to about 0.5 molar concentration of an acid. Also provided are copper damascene structures having an aspect ratio of greater than about 3 and a width of less than about 0.275 μm and via openings filled with electroplated copper than is substantially free of internal seams or voids.

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A Model of Superfilling in Damascene Electroplating; H. Deligianni, et al.; The 195thMeeting of Electrochemical Society, Inc. Meeting Abstracts, vol. 99-1 (May 2-6, 1999).
Model of Wafer Thickness Uniformity in an Electroplating Tool;The 195thMeeting of Electrochemical Society, Inc. Meeting Abstracts, vol. 99-1 (May 2-6, 1999).
A Model of Superfilling in Damascene Electroplating; H. Deligianni, et al.: Electrochemical Processing in USLI Fabrication and Semiconductor/Metal Deposition II: Proceedings of the International Symposium; P.C.; Uziel Landau, et al., The Electrochemical Society, Inc, Proceedings vol. 99-9.
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Model of Wafer Thickness Uniformity in an Electrocoplating Tool; Electrochemical Processing in ULSI Fabrication and Semiconductor/Metal Deposition II: Proceedings of the International Symposium; P.C.H. Deligiannni, et al., The Electrochemical Society, Inc., Proceedings vol. 99-9.
Computational Aspects of the Terminal Effect on Wafer-Scale Uniformity: H. Deligianni et al.; The 195thMeeting of Electrochemical Society, Inc. Meeting Abstracts, vol. 99-1 (May 2-6, 1999).

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