Bi-layer photoresist dry development and reactive ion etch...

Details Bi-layer photoresist dry development and reactive ion etch... Bi-layer photoresist dry development and reactive ion etch...

2002-01-08

2004-04-13

Huff, Mark F. (Department: 1756)

Radiation imagery chemistry: process, composition, or product th

Imaging affecting physical property of radiation sensitive...

Making electrical device

C430S311000, C430S313000, C430S317000, C216S067000, C438S710000, C438S725000

Reexamination Certificate

active

06720132

ABSTRACT:

FIELD OF THE INVENTION
This invention generally relates to photoresist methods for forming semiconductor features and more particularly to a bi-layer photoresist dry development method for high resolution features included in a continuous process including reactive ion etching.
BACKGROUND OF THE INVENTION
In semiconductor fabrication, various layers of insulating material, semiconducting material and conducting material are formed to produce a multilayer semiconductor device. The layers are patterned to create features that taken together, form elements such as transistors, capacitors, and resistors. These elements are then interconnected to achieve a desired electrical function, thereby producing an integrated circuit (IC) device. The formation and patterning of the various device layers are achieved using conventional fabrication techniques, such as oxidation, implantation, deposition, epitaxial growth of silicon, lithography, etching, and planarization.
As devices continue to shrink in size, the limits of processing technologies are reached requiring new and cost effective innovations. For example, acceptable photoresist imaging is one limiting technology that has required the adoption of new approaches as finer imaging resolutions are sought to meet the requirements of smaller device sizes. For example, single layer photoresist layers have the problem that they need both effective etching resistance and depth of focus (DOF) requirement. However, the former requirement calls for thicker photoresist layers while the latter requirement calls for thinner photoresist layers. One approach has been to move to bi-layer and tri-layer photoresist layers where the uppermost photoresist layer is used for imaging thereby allowing a thinner image layer and acceptable depth of focus (DOF) with a larger photo-window. Consequently, resolution, and pattern width control are enhanced.
A corresponding requirement to achieve high resolution features and critical dimension control is an effective development process. Wet processing techniques have increasingly become inadequate due to several problems including photoresist poisoning of features by leaving undeveloped photoresist caused by either or both, step height limitations affecting the photo imaging process or by residual nitrogen contaminating species interfering with photoresist exposure and development processes.
As such, dry development processes involving plasma etching have been increasingly adopted leading to improved etching profiles. However, dry etching (plasma etching) has demonstrated problems of its own including, for example, critical dimension bias between isolated and dense line areas where, due to microloading, isolated lines etch faster than dense lines leading to unacceptable differences in critical dimension. For example, in single layer photoresists, dry development of, for example, via holes, leads to roughened hole edges or “striation”. If a hard mask, such as a metal nitride, is used over the inter-layer dielectric (ILD) insulating layer, the via hole edges are tapered to wider dimension referred to as “top CD blow out”. Bi-layer approaches have led to some improvement in dry etching critical dimension control, however, further improvement is need in etching selectivity in dry development as resolution demands are increased, for example with 193 nm and 157 nm photoresists.
For example, more recent shorter wavelength photoresist approaches have used a surface modification technique where the surface of a photoresist film is silylated after the exposure to light. Following exposure, a dry development process is used to form a pattern having good resolution and resistance to dry etching. According to this technique, an initial pattern is formed in a region of about 1000 Angstroms of thickness within of the photoresist film. The silylated surface layer is intended to protect the lower layer from premature etching thus resulting in better selectivity and smoother etching profiles following dry etching of a feature. However, at the dry development stage, the plasma etching procedure according to the prior art has the shortcoming that the sidewalls of the underlying photoresist layer may be over-etched, causing a tapered cross section and loss of critical dimension. Sidewall etching of the underlying photoresist layer in the bi-layer approach with surface layer silylation is believed to occur since the silylation is limited to about the first 200 to 300 Angstroms adjacent the surface of the upper photoresist layer. As a result, the stability of the pattern deteriorates as the dry etching development process proceeds through the photoresist layers.
In the prior art, the dry development etching process has used a sulfur dioxide (SO
2
) based chemistry including oxygen (O
2
). Sulfur dioxide (SO
2
) based chemistry in dry development forms a passivating layer on the sidewalls of the photoresist layers thereby, in theory, increasing the anisotropicity of the etching process to reduce the microloading effects. However, as mentioned, the sulfur dioxide dry development chemistry has limitations, including continued problems with loss of critical dimension during dry development.
For example, one problem associated with the sulfur dioxide (SO
2
) based chemistry dry development of the prior art include corrosive effects believed to be related to the formation of sulfuric acid, e.g. (H
2
SO
4
) leading to corrosion of, for example, copper-filled vias and trenches causing degradation of the copper layers to include peeling of the copper layers. In addition, other features of multi-layer semiconductor devices included in a semiconductor process wafer are generally adversely affected by corrosive action. Yet another adverse effect associated with sulfur dioxide (SO
2
) based chemistry in dry development processes is the formation of water (H2O) during the dry development process leading to moisture adsorption by low-k (dielectric constant) layers and subsequently to via poisoning.
Another problem with prior art dry development processes is the requirement that photoresist dry development, photoresist layer removal (ashing), and feature etching typically require separate plasma reactors due the large number of residual particles generated during the ashing or feature etching process. Consequently there is a high probability of contamination in the photoresist dry development of the prior art if for example, an ashing process in a separate chamber follows dry development prior to feature etching whereby movement of the semiconductor wafer from one plasma chamber to another increases the likelihood of particle contamination. As a result, the dry development procedure according to the prior art is equipment and time intensive, with residual particle contamination issues, leading to higher manufacturing expense.
There is therefore a need in the semiconductor processing art to develop a more reliable bi-layer photoresist dry development process with high resolution that may be carried out without the corrosion problems and particle contamination problems associated with the prior art dry development methods.
It is therefore an object of the invention to provide to develop a more reliable bi-layer photoresist dry development process with high resolution that may be carried out without the corrosion problems and particle contamination problems associated with the prior art dry development methods while overcoming other shortcomings and deficiencies in the prior art.
SUMMARY OF THE INVENTION
To achieve the foregoing and other objects, and in accordance with the purposes of the present invention, as embodied and broadly described herein, the present invention provides a method for semiconductor device feature development using a bi-layer photoresist.
In a first embodiment according to the present invention, a method is provided including the steps of providing a non-silicon containing photoresist layer over a substrate; providing a silicon containing photoresist layer over the non-silicon containing photoresist layer; exposing an exposure sur

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