Atomic layer-deposited LaAlO3 films for gate dielectrics

Semiconductor device manufacturing: process – Making field effect device having pair of active regions... – Having insulated gate

Reexamination Certificate

Rate now

  [ 0.00 ] – not rated yet Voters 0   Comments 0

Details

C438S643000, C438S003000

Reexamination Certificate

active

07045430

ABSTRACT:
A dielectric film containing LaAlO3and method of fabricating a dielectric film contained LaAlO3produce a reliable gate dielectric having a thinner equivalent oxide thickness than attainable using SiO2. The LaAlO3gate dielectrics formed are thermodynamically stable such that these gate dielectrics will have minimal reactions with a silicon substrate or other structures during processing. A LaAlO3gate dielectric is formed by atomic layer deposition employing a lanthanum sequence and an aluminum sequence. A lanthanum sequence uses La(thd)3(thd=2,2,6,6-tetramethyl-3,5-heptanedione) and ozone. An aluminum sequence uses either trimethylaluminum, Al(CH3)3, or DMEAA, an adduct of alane (AlH3) and dimethylethylamine [N(CH3)2(C2H5)], with distilled water vapor.

REFERENCES:
patent: 4058430 (1977-11-01), Suntola et al.
patent: 4215156 (1980-07-01), Dalal et al.
patent: 4333808 (1982-06-01), Bhattacharyya et al.
patent: 4394673 (1983-07-01), Thompson et al.
patent: 4399424 (1983-08-01), Rigby
patent: 4413022 (1983-11-01), Suntola et al.
patent: 4647947 (1987-03-01), Takeoka et al.
patent: 4725877 (1988-02-01), Brasen et al.
patent: 4920071 (1990-04-01), Thomas
patent: 5055319 (1991-10-01), Bunshah et al.
patent: 5080928 (1992-01-01), Klinedinst et al.
patent: 5198029 (1993-03-01), Dutta et al.
patent: 5496597 (1996-03-01), Soininen et al.
patent: 5595606 (1997-01-01), Fujikawa et al.
patent: 5698022 (1997-12-01), Glassman et al.
patent: 5795808 (1998-08-01), Park
patent: 5801105 (1998-09-01), Yano et al.
patent: 5810923 (1998-09-01), Yano et al.
patent: 5822256 (1998-10-01), Bauer et al.
patent: 5828080 (1998-10-01), Yano et al.
patent: 5840897 (1998-11-01), Kirlin et al.
patent: 5916365 (1999-06-01), Sherman
patent: 5972847 (1999-10-01), Feenstra et al.
patent: 6010969 (2000-01-01), Vaartstra
patent: 6013553 (2000-01-01), Wallace et al.
patent: 6020024 (2000-02-01), Maiti et al.
patent: 6027961 (2000-02-01), Maiti et al.
patent: 6057271 (2000-05-01), Kenjiro et al.
patent: 6093944 (2000-07-01), VanDover
patent: 6110529 (2000-08-01), Gardiner et al.
patent: 6171900 (2001-01-01), Sun
patent: 6203613 (2001-03-01), Gates et al.
patent: 6203726 (2001-03-01), Danielson et al.
patent: 6207589 (2001-03-01), Ma et al.
patent: 6211035 (2001-04-01), Moise et al.
patent: 6225168 (2001-05-01), Gardner et al.
patent: 6225237 (2001-05-01), Vaartstra
patent: 6273951 (2001-08-01), Vaartstra
patent: 6297539 (2001-10-01), Ma et al.
patent: 6303481 (2001-10-01), Park
patent: 6368398 (2002-04-01), Vaartstra
patent: 6368941 (2002-04-01), Chen et al.
patent: 6380579 (2002-04-01), Nam et al.
patent: 6387712 (2002-05-01), Yano et al.
patent: 6391769 (2002-05-01), Lee et al.
patent: 6395650 (2002-05-01), Callegari et al.
patent: 6404027 (2002-06-01), Hong et al.
patent: 6420230 (2002-07-01), Derderian et al.
patent: 6432779 (2002-08-01), Hobbs et al.
patent: 6436203 (2002-08-01), Kaizuka et al.
patent: 6441417 (2002-08-01), Zhang et al.
patent: 6445023 (2002-09-01), Vaartstra et al.
patent: 6448192 (2002-09-01), Kaushik
patent: 6451641 (2002-09-01), Halliyal et al.
patent: 6451695 (2002-09-01), Sneh
patent: 6452229 (2002-09-01), Krivokapic
patent: 6458701 (2002-10-01), Chae et al.
patent: 6465334 (2002-10-01), Buynoski et al.
patent: 6482740 (2002-11-01), Soininen et al.
patent: 6495436 (2002-12-01), Ahn et al.
patent: 6521911 (2003-02-01), Parsons et al.
patent: 6531324 (2003-03-01), Hsu et al.
patent: 6531354 (2003-03-01), Maria et al.
patent: 6537613 (2003-03-01), Senzaki et al.
patent: 6555879 (2003-04-01), Krivokapic et al.
patent: 6586349 (2003-07-01), Jeon et al.
patent: 6602720 (2003-08-01), Hsu et al.
patent: 6620670 (2003-09-01), Song et al.
patent: 6627260 (2003-09-01), Derderian et al.
patent: 6645882 (2003-11-01), Halliyal et al.
patent: 6660660 (2003-12-01), Haukka et al.
patent: 6713846 (2004-03-01), Senzaki
patent: 6730575 (2004-05-01), Eldridge
patent: 6750066 (2004-06-01), Cheung et al.
patent: 6950340 (2005-09-01), Bhattacharyya
patent: 6952032 (2005-10-01), Forbes et al.
patent: 6979855 (2005-12-01), Ahn et al.
patent: 2002/0001971 (2002-01-01), Cho
patent: 2002/0024108 (2002-02-01), Lucovsky et al.
patent: 2002/0025628 (2002-02-01), Derderian et al.
patent: 2002/0089023 (2002-07-01), Yu et al.
patent: 2002/0111001 (2002-08-01), Ahn et al.
patent: 2002/0122885 (2002-09-01), Ahn
patent: 2002/0155688 (2002-10-01), Ahn et al.
patent: 2002/0155689 (2002-10-01), Ahn et al.
patent: 2002/0164420 (2002-11-01), Derderian et al.
patent: 2002/0192974 (2002-12-01), Ahn et al.
patent: 2003/0003722 (2003-01-01), Vaartstra
patent: 2003/0017717 (2003-01-01), Ahn et al.
patent: 2003/0045082 (2003-03-01), Eldridge et al.
patent: 2003/0072882 (2003-04-01), Niinisto et al.
patent: 2003/0119291 (2003-06-01), Ahn et al.
patent: 2003/0157764 (2003-08-01), Ahn et al.
patent: 2003/0207032 (2003-11-01), Ahn et al.
patent: 2003/0207593 (2003-11-01), Derderian
patent: 2003/0209324 (2003-11-01), Fink
patent: 2003/0227033 (2003-12-01), Ahn et al.
patent: 2003/0228747 (2003-12-01), Ahn et al.
patent: 2004/0004245 (2004-01-01), Forbes et al.
patent: 2004/0004247 (2004-01-01), Forbes et al.
patent: 2004/0033681 (2004-02-01), Ahn et al.
patent: 2004/0033701 (2004-02-01), Ahn et al.
patent: 2004/0038525 (2004-02-01), Meng et al.
patent: 2005/0138262 (2005-06-01), Forbes
patent: 2005/0277256 (2005-12-01), Ahn et al.
patent: 2005/0280067 (2005-12-01), Ahn et al.
patent: 1096042 (2001-05-01), None
patent: 1124262 (2001-08-01), None
patent: 11-335849 (1999-12-01), None
patent: 2001-332546 (2001-11-01), None
patent: WO-02/31875 (2002-04-01), None
patent: WO-0233729 (2002-04-01), None
patent: WO-02/43115 (2002-05-01), None
Kim et al., “Atomic Control of Substrate Termination and Heteroepitaxial Growth of SrTiO3/LaAlO3 Films” Jun. 2000, Journal of the Korean Physical Society, vol. 36 No. 6, pp. 444-448.
Clark-Phelps, R. B., et al., “Engineered Tantalum Aluminate and Hafnium Aluminate ALD Films for Ultrathin Dielectric Films with Improved Electric and Thermal Properties”,Gate Stack and Silicide Issues in Silicon Processing II, Symposium(Materials Research Society Symposium Proceedings vol. 670), (Apr. 17, 2001),K2.2.1-6.
Lee, Jung-Hyoung , et al., “Mass production worthy HfO/sub 2/-Al/sub 2/O/sub 3/ laminate capacitor technology using Hf liquid precursor for sub-100 nm DRAMs”,Electron Devices Meeting, 2002. IEDM '02. Digest. International, (2002),221-224.
Oh, C B., et al., “Manufacturable embedded CMOS 6T-SRAM technology with high-k gate dielectric device for system-on-chip applications”,Technical Digest of International Electron Devices Meeting 2002, (2002),423-426.
Ahn, Seong-Deok , et al., “Surface Morphology Improvement of Metalorganic Chemical Vapor Deposition Al Films by Layered Deposition of Al and Ultrathin TiN”,Jpn. J. Appl. Phys. vol. 39(2000)3349-3354, (Jun. 2000),3349-3354.
Alen, Petra , et al., “Atomic Layer Deposition of Ta(Al)N(C) Thin Films Using Trimethylaluminum as a Reducing Agent”,Journal of Electrochemical Society, 148(10),pp. G566-G571(2001). From disclosure of 1303.068US1,(2001),pp. G566-G571.
Elam, J W., “Kinetics of the WF6 and Si2H6 surface reactions during tungsten atomic layer deposition”,Surface Science, vol. 479,(2001),pp. 121-135.
Gusev, E P., et al., “Ultrathin High-K Dielectrics Grown by Atomic Layer Deposition: A Comparative Study of ZrO2, HfO2, Y2O3 and Al2O3”,Electrochemical Society Proceedings vol. 2001-9, (2001),pp. 189-195.
Aarik, Jaan.,et al. ,“Texture development in nanocrystalline hafnium dioxide thin films grown by atomic layer deposition”,Journal of Crystal Growth, (2000), pp. 105-113.
Cheng, Baohong.,et al. ,“The Impact of High-k Gate Dielectrics and Metal Gate Electrodes on Sub-100nm MOSFET's”,IEEE Transactions on Electron Devices, (1999), pp. 1537-1544.
Desu, S.B..,“Minimization of Fatigue in Ferroelectric Films”,Phys. Stat. Sol.(a)151, (1995), pp. 467-480.
Engelhardt, M..,“Modern Applications of Plasma Etching and Patterning in Si

LandOfFree

Say what you really think

Search LandOfFree.com for the USA inventors and patents. Rate them and share your experience with other people.

Rating

Atomic layer-deposited LaAlO3 films for gate dielectrics does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Atomic layer-deposited LaAlO3 films for gate dielectrics, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Atomic layer-deposited LaAlO3 films for gate dielectrics will most certainly appreciate the feedback.

Rate now

     

Profile ID: LFUS-PAI-O-3571315

  Search
All data on this website is collected from public sources. Our data reflects the most accurate information available at the time of publication.