Method for forming low-k hard film

Semiconductor device manufacturing: process – Coating of substrate containing semiconductor region or of... – Insulative material deposited upon semiconductive substrate

Reexamination Certificate

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C438S788000, C438S789000, C438S790000

Reexamination Certificate

active

07064088

ABSTRACT:
A hard film is formed on an insulation film formed on a semiconductor substrate by vaporizing a silicon-containing hydrocarbon compound to provide a source gas, introducing a reaction gas composed of the source gas and optionally an additive gas such as alcohol to a reaction space of a plasma CVD apparatus, and applying low-frequency RF power and high-frequency RF power. The silicon-containing hydrocarbon compound includes a cyclic Si-containing hydrocarbon compound and/or a linear Si-containing hydrocarbon compound, as a basal structure, with reactive groups for form oligomers using the basal structure. The residence time of the reaction gas in the reaction space is lengthened by reducing the total flow of the reaction gas in such a way as to form a siloxan polymer film with a low dielectric constant.

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patent: 1 225 194 (2002-07-01), None
U.S. Appl. No. 10/317,239, filed Dec. 11, 2002, Matsuki et al.
U.S. Appl. No. 10/351,669, filed Jan. 24, 2003, Tsuji et al.
U.S. Appl. No. 10/402,109, filed Mar. 27, 2003, Matsuki et al.

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