Semiconductor device and method for manufacturing the same

Semiconductor device manufacturing: process – Making field effect device having pair of active regions... – Having insulated gate

Reexamination Certificate

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C438S211000, C438S218000, C438S527000, C438S592000, C438S655000, C438S659000

Reexamination Certificate

active

06638803

ABSTRACT:

BACKGROUND OF THE INVENTION
1. Field of the Invention
The present invention relates to a semiconductor device and a method for manufacturing the same. More particularly, the invention relates to a semiconductor device comprising MOS (metal oxide semiconductor) transistors and a method for manufacturing that semiconductor device.
2. Description of the Background Art
FIGS. 4A through 4F
are cross-sectional views showing structures of conventional MOS transistors and steps to fabricate such transistors. These steps constitute a method for producing MOS transistors containing within their gate electrodes a stacked film made of tungsten silicide (WSi) and polysilicon, i.e., MOS transistors in a WSi-polycide structure. The steps also make up a method for having NMOS transistors and PMOS transistors formed adjacent to one another on a single substrate.
Conventionally, as shown in
FIG. 4A
, isolation regions
12
are first formed to a depth of 4,000 angstroms by use of an insulating film such as an oxide film on a silicon substrate
10
. The isolation regions
12
are laid out so as to isolate NMOS and PMOS regions (where NMOS and PMOS transistors are to be formed respectively) from one another on the silicon substrate
10
(step
1
).
The silicon substrate
10
is arranged so that the NMOS regions will serve as P-type semiconductors and PMOS regions as N-type semiconductors (step
2
).
On the surface of the silicon substrate
10
, a silicon oxide film
14
to be used later as a gate insulating film is formed to a thickness of 40 angstroms (step
3
).
On the silicon oxide film
14
, polysilicon is deposited by low-pressure CVD. This forms a polysilicon film
16
having a thickness of 1,000 angstroms (step
4
).
On the polysilicon film
16
, a resist film
18
is patterned so as to expose the NMOS regions while covering the PMOS regions (step
5
).
With the resist film
18
used as a mask, N-type impurities consisting of phosphorus (P) are injected at 10 keV with a density of 8×10
15
atoms/cm
2
into the NMOS regions of the polysilicon film
16
(step
6
).
As depicted in
FIG. 4B
, a resist film
20
is patterned so as to expose the PMOS regions while covering the NMOS regions on the polysilicon film
16
(step
7
).
Then with the resist film
20
used as a mask, P-type impurities consisting of BF
2
are injected at 10 keV with a density of 6×10
15
atoms/cm
2
into the PMOS regions of the polysilicon film
16
(step
8
).
As indicated in
FIG. 4C
, a WSi film
22
with a thickness of 1,000 angstroms is formed on the polysilicon film
16
(step
9
).
On the WSi film
22
, a resist film
24
is patterned so as to expose the NMOS regions while covering the PMOS regions (step
10
).
With the resist film
24
used as a mask, N-type impurities consisting of phosphorus (P) are injected at 30 keV with a density of 2×10
15
atoms/cm
2
into the NMOS regions of the WSi film
22
(step
11
).
As shown in
FIG. 4D
, a resist film
26
is patterned on the WSi film
22
so as to expose the PMOS regions while covering the NMOS regions (step
12
).
With the resist film
26
used as a mask, P-type impurities consisting of boron (B) are injected at 10 keV with a density of 4×10
15
atoms/cm
2
into the PMOS regions of the WSi film
22
(step
13
).
On the WSi film
22
, as depicted in
FIG. 4E
, a silicon oxide film
28
with a thickness of 1,000 angstroms is formed (step
14
).
Thereafter, a silicon nitride film
30
with a thickness of 500 angstroms is formed on the silicon oxide film
28
(step
15
).
On the silicon nitride film
30
, a resist film
32
is formed. The resist film
32
thus furnished is patterned into gate electrodes by photolithography (step
16
).
As indicated in
FIG. 4F
, the silicon nitride film
30
is patterned into gate electrodes by etching, with the resist film
32
used as a mask (step
17
).
The silicon nitride film
30
thus patterned is used as a mask for anisotropic etching whereby the silicon oxide film
28
, WSi film
22
, polysilicon film
16
and silicon oxide film
14
are patterned successively into gate electrodes (step
18
).
N-type impurities are injected into the NMOS regions of the silicon substrate in order to form LDD (Lightly Doped Drain) regions. P-type impurities are injected into the PMOS regions of the substrate to form the same type of regions (step
19
).
An insulating film such as a silicon oxide film is deposited all over the wafer. The insulating film thus furnished is subjected to anisotropic etching whereby sidewalls
33
protecting the sides of the gate electrodes are formed (step
20
).
N-type impurities are injected into the NMOS regions of the silicon substrate in order to form source and drain regions of the NMOS transistors. P-type impurities are injected into the PMOS regions of the substrate to form source and drain regions of the PMOS transistors (step
21
).
As described, the conventional manufacturing method involves injecting N-type impurities (such as phosphorus) or P-type impurities (B, BF
2
, etc.) are injected into the polysilicon film
16
and WSi film
22
. The injected impurities are later activated by suitable heat treatments to contribute significantly to providing electric conduction. polysilicon film
16
and WSi film
22
. The injected impurities are later activated by suitable heat treatments to contribute significantly to providing electric conduction.
In recent years, diversification of data processing applications has entailed the development of system LSIs that combine a semiconductor memory with a logic LSI. For example, an eDRAM (embedded DRAM) combining a DRAM (Dynamic Random Access Memory) with a logic LSI is known as a system LSI capable of processing massive image data at high speed.
Steps for combining a DRAM with a logic LSI to fabricate a system LSI (eDRAM) may sometimes involve numerous heat treatments following the formation of MOS transistors to be included in the system LSI. During such heat treatments, impurities in the gate electrodes of the MOS transistors can diffuse into a gate insulating film or like components, resulting in a reduced density of impurities in the gate electrodes.
Such a drop in the impurity density of the gate electrodes or a sustained inactive state of the impurities in the electrodes may lead to a depletion layer in the electrodes getting inordinately large in proportion, a phenomenon called gate electrode depletion. The diffusion of impurities in the gate electrodes (gate electrode depletion) can trigger changes in MOS transistor characteristics. For these reasons, the conventional method has been associated with the problem of fluctuating MOS transistor characteristics, especially when applied to the fabrication of the system LSI.
SUMMARY OF THE INVENTION
It is therefore a first object of the present invention to overcome the above and other deficiencies of the prior art and to provide MOS transistors capable of exerting their required characteristics after undergoing heat treatments during DRAM fabrication processes.
It is a second object of the present invention to provide a method suitable for manufacturing the inventive MOS transistors.
The above objects of the present invention are achieved by a semiconductor device described below. The semiconductor device includes a silicon substrate. A gate insulating film is formed on the silicon substrate. A gate electrode is formed on the gate insulating film. The gate electrode includes an amorphous silicon film formed on the gate insulating film, a tungsten silicide film formed on the amorphous silicon film, and an insulating film formed on the tungsten silicide film.
The above objects of the present invention are also achieved by A method for manufacturing a semiconductor device including MOS transistors. In the manufacturing method, an isolation region is formed on a silicon substrate so as to isolate a plurality of MOS regions in which to form MOS transistors. A first insulating film is formed as a gate insulating film on the silicon substrate. An amorphous silicon film is formed on the first insula

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