Method of manufacturing a flash memory device

Semiconductor device manufacturing: process – Making field effect device having pair of active regions... – Having insulated gate

Reexamination Certificate

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C438S264000, C438S266000

Reexamination Certificate

active

06531360

ABSTRACT:

This application relies for priority upon Korean Patent Application No. 2000-60033, filed on Oct. 12, 2000, the contents of which are herein incorporated by reference in their entirety.
BACKGROUND OF THE INVENTION
In a flash memory device, increased integration, improved operating efficiency or performance, and insurance of mass productivity are very important goals that should be continuously improved and developed. However, because of the complex elements incorporated into the flash memory device, it is not easy to simultaneously achieve these goals.
The complexity of the integrated elements results from the operating characteristics of the flash memory device. Namely, the flash memory device, a nonvolatile memory type, is designed to have three operating modes—programming, erasing, and reading data. In order to carry out these three modes, the flash memory device needs to form high and low voltage transistors in a peripheral circuit area thereof along with transistors having double gates in a cell area thereof. The gate insulating layer and source/drain regions in the high voltage transistor can be formed to have respectively different thickness and structure compared with those in the low voltage transistor. Also, the peripheral circuit area of the flash memory device generally has a complementary metal oxide silicon (CMOS) structure which, like that of other memory devices, simultaneously uses p-channel and n-channel transistors to increase efficiency or performance.
As element complexity increases, the processes required to manufacture a flash memory device also become more complicated and difficult. Among the characteristics of the flash memory device, the endurance characteristic showing whether or not thermal damage has occurred with repeated programming and erasing and the data retention characteristic showing how long it continues to store data after programming are both important. The endurance and data retention characteristics are dependent on the quality of a dielectric layer and a gate insulating layer which are in contact with floating gates in a cell area of the flash memory device. Also, the characteristics of high and low voltage transistors in a peripheral circuit area, which has a large influence on functional operation of the flash memory device, is dependent on the quality of the gate insulating layer. However, it is not easy to form both a superior gate insulating layer and quality dielectric layer.
FIG. 1
is a top plan view showing a portion of a cell area of a general NOR type flash memory.
Referring now to
FIG. 1
, isolation areas
11
are formed on a substrate to form an active region. The active region comprises a plurality of longitudinal band shaped sub-regions which are defined respectively by a plurality of longitudinal openings or gaps of the isolation areas
11
. Floating gates
15
are disposed between word lines
13
and the active region on the portions of the substrate surfaces where the word lines
13
overlay the active region. The floating gates
15
are separated from the word lines
13
and the active region by a dielectric layer and a gate insulating layer, respectively. Also, each floating gate
15
partially overlaps an isolation area
11
at both of its edges. Source lines
17
, positioned parallel to the word lines
13
, are formed by removing portions of the isolation area
11
positioned on the surface of the substrate using the word lines
13
as a mask, and then carrying out ion implantation on the exposed surface of the substrate. Contacts
19
, with which bit lines
21
are connected, are formed in a drain region between the word lines
13
disposed between the source lines
17
.
FIG. 2
to
FIG. 4
are cross-sectional views of a semiconductor device showing the sequential formation of layers used in a conventional method of manufacturing a NOR type flash memory device. In the drawings, the processes of depositing and etching materials to form transistors in a cell area and transistors in high and low voltage regions of a peripheral circuit area are illustrated step by step. The cell area is shown as a section taken along the direction of the word lines, and the peripheral circuit area is shown as a section taken along the direction of connecting source/drain regions without dividing p-channel and n-channel.
Referring now to
FIG. 2
, isolation area
11
are formed on a substrate
10
to define an active region. Then, a buffer oxide layer
12
is formed on the active region of the substrate
10
. In order to form all sorts of impurity wells, various ion implantation processes are performed. Each process is composed of forming an ion implantation mask according to the region to be implanted, carrying out ion implantation operations and removing the ion implantation mask.
Referring to
FIG. 3
, the buffer oxide layer
12
(from
FIG. 2
) in a cell region is removed and then a tunneling gate insulating layer
121
is formed. Thereafter, a floating gate layer is deposited on the tunneling gate insulating layer
121
and patterned to form a floating gate layer pattern
131
. Then, an oxide-nitride-oxide (ONO) dielectric layer
141
is formed over the whole surface of the substrate to cover the floating gate layer pattern
131
. Thereafter, an etch mask
143
is formed of a photoresist to cover the cell region, and the dielectric layer
141
, the floating gate layer
131
, and the buffer oxide layer
12
covering the active region in the peripheral circuit area are removed, so that surface of the active region in the peripheral circuit area is exposed. Then, the etch mask
143
is removed.
In succession, ion implantation processes for controlling threshold voltages of the high and low voltage transistors are carried out.
Referring to
FIG. 4
, a gate insulating layer
222
′ for the high voltage region is formed in the peripheral circuit area. Then, an etch mask, which exposes a low voltage region of the peripheral circuit area, is used to remove the portion of gate insulating layer
222
′ covering the low voltage region. After removing the high voltage gate insulating layer
222
′ formed in the low voltage region, the etch mask is removed and a gate insulating layer
223
is formed in the low voltage region. The gate insulating layers
222
′,
223
are formed of a silicon oxide layer which is made of thermally oxidized silicon. A silicon oxide layer is used rather than a silicon oxide nitride layer, otherwise a silicon oxide layer of the ONO dielectric layer
141
in the cell area exposed after the etch mask
143
is removed can be nitrified, negatively influencing the permittivity.
Next, a control gate layer
151
is deposited over the whole surface of the substrate and patterned to form word lines. While forming word lines in the cell region, the dielectric layer
141
and the floating gate layer
131
in the rest of the cell regions not overlaid by word lines are also removed by etching. Source lines positioned parallel to the word lines are formed by removing portions of the isolation area
11
positioned between the word lines using an etch mask pattern and the word lines as a mask, and then carrying out ion implantation in the exposed surface of the substrate. At this time, ion implantation is also carried out against a drain region. Thereafter, gate electrodes
153
for high and low voltage transistors are formed by patterning the control gate layer
151
.
In the conventional method of manufacturing flash memory devices explained above, the dielectric layer
141
is generally formed of an ONO layer. Also, in several process steps, photoresist patterns are formed as etch or ion implantation masks on the dielectric layer
141
and/or the surface of the substrate
10
. In particular, after the dielectric layer is formed over the whole surface of the substrate, a patterning process which forms a photoresist pattern on the dielectric layer is carried out. Also, in order to carry out ion implantation processes for controlling threshold voltages of the high and low voltage transistors, photoresist pat

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