Chemistry: electrical and wave energy – Processes and products – Coating – forming or etching by sputtering
Reexamination Certificate
2001-09-12
2004-08-31
VerSteeg, Steven (Department: 1753)
Chemistry: electrical and wave energy
Processes and products
Coating, forming or etching by sputtering
C204S192230, C430S005000
Reexamination Certificate
active
06783634
ABSTRACT:
This application claims the Paris convention priority of Japanese patent application 2000-277354 filed on Sep. 12, 2000, the entire disclosure of which is incorporated herein by reference.
BACKGROUND OF THE INVENTION
i) Field of the Invention
The present invention relates to a manufacturing method and apparatus of a phase shift mask blank which is suitable particularly for ArF or F
2
excimer laser.
ii) Description of the Related Art
In recent years, it has been clarified that high resolution and focus depth are two important properties required for photolithography but are in a contradictory relation with each other, and that a practical resolution cannot be enhanced only by high NA and short wavelength of a lens of an exposure apparatus (Monthly Semiconductor World 1990.12, Applied Physics Vol. 60, November, 1991, and the like).
Under such situation, phase shift lithography has been noted as the next-generation photolithography technique, and partially brought to practical use. The phase shift lithography is a method for enhancing the resolution of photolithography by change only of a mask without changing an optical system. When a phase difference is applied between exposure lights transmitted through the photo mask, mutual interference of the transmitted lights can be utilized to rapidly enhance the resolution.
The phase shift mask is a mask for using light strength information together with phase information. Various types of the masks are known such as Levenson type, auxiliary pattern type, and self-matching type (edge emphasizing type). These phase shift masks have a complicated constitution and requires a high degree of manufacturing technique as compared with the conventional photo mask which has only the light strength information.
In recent years, a so-called halftone type phase shift mask has been developed as one of the phase shift masks.
In the halftone phase shift mask, a light semi-transmission section has two functions: a shield function of substantially shielding the exposure light; and a phase shift function of shifting (usually reversing) a light phase. Therefore, it is unnecessary to separately form a shield film pattern and phase shift film pattern. This type of phase shift mask is simple in constitution and easy in manufacturing.
In the halftone phase shift mask, a mask pattern is processed by a dry etching process. However, in a method of realizing the shield function and phase shift function by separate layers, a high degree of control is necessary for both the layer having the shield function and the layer having the phase shift function in order to obtain a satisfactory pattern shape. On the other hand, when a single-layer light semi-transmission portion having both the shield function and the phase shift function is constituted, a single etching process can be used. Therefore, a manufacturing process of the mask can be simplified, and a satisfactory pattern shape can easily be obtained.
For the halftone phase shift mask, as shown in
FIG. 10
, a mask pattern formed on a transparent substrate
100
is constituted of a light transmission portion (transparent substrate exposed portion)
200
for transmitting a light which is strong enough to substantially contribute to exposure, and a light semi-transmission portion (shield and phase shifter portion)
300
for transmitting a light which is not strong enough to substantially contribute to the exposure (FIG.
10
A). Additionally, the phase of the light transmitted to the light semi-transmission portion is shifted, and the light semi-transmission portion is brought to a substantially reversed relation with respect to the phase of the light transmitted through the light transmission portion (FIG.
10
B). The lights transmitted in the vicinity of a boundary between the light semi-transmission portion and the light transmission portion and turned to the opposite portions by diffraction phenomenon cancel each other. Thereby, light strength in the boundary is substantially set to zero, and contrast, that is, resolution of the boundary is enhanced (FIG.
10
C).
Additionally, the light semi-transmission portion or film (phase shift layer) in the halftone phase shift mask or blank needs to indicate a required optimum value with respect to both transmittance and phase shift amount. Concretely, (1) the transmittance in exposure wavelength of i-ray, KrF excimer laser, ArF excimer laser, or the like can be adjusted in a range of 3 to 20%, (2) a phase angle can be adjusted usually to a value in the vicinity of 180° in the exposure wavelength, and (3) the transmittance needs to be usually testable in a range of 65% or less in test wavelengths such as 257 nm, 266 nm, 364 nm, and 488 nm.
However, with shortening of the wavelength of laser for use in exposure to ArF excimer laser (193 nm) from i-ray (365 nm) and KrF excimer laser (248 nm), the following problem is generated in the conventional halftone phase shift mask and the manufacturing method of the mask.
That is, in mass production of the phase shift mask blanks, when there are dispersions of the phase angle and transmittance among the blanks or in the plane, yield is bad. Particularly in the mask blanks for the short wavelength of ArF or F
2
excimer laser, the dispersions of the phase angle and transmittance among the blanks and in the plane in the conventional mask blanks for i-ray and KrF excimer laser are large, and the yield is bad. Therefore, the mask blanks cannot be applied as they are.
SUMMARY OF THE INVENTION
The present invention has been developed under the aforementioned background, and a first object thereof is to provide a manufacturing method of a phase shift mask blank in which dispersions of a phase angle and transmittance among blanks can be reduced as much as possible and a yield is satisfactory.
Moreover, a second object is to provide a manufacturing method of the phase shift mask blank in which the dispersions of the phase angle and transmittance in a plane of the blanks can be reduced as much as possible and the yield is satisfactory.
Furthermore, a third object is to provide a manufacturing apparatus of the phase shift mask blank in which the dispersions of the phase angle and transmittance among the blanks can be reduced as much as possible and which can be manufactured with a satisfactory yield.
Additionally, a fourth object is to provide a manufacturing apparatus of the phase shift mask blank in which the dispersions of the phase angle and transmittance in the plane of the blanks can be reduced as much as possible and which can be manufactured with the satisfactory yield.
To achieve the aforementioned objects, the present invention has the following constitutions.
(Constitution 1) A method of continuously manufacturing a plurality of phase shift mask blanks each having at least a phase shift film on a transparent substrate, the method comprising a step of:
using a sputtering method to continuously form the phase shift film on the transparent substrate,
wherein a dispersion of a phase angle of the phase shift film among the plurality of blanks is within ±2°.
(Constitution 2) A method of continuously manufacturing a plurality of halftone phase shift mask blanks each having at least a light semi-transmission film on a transparent substrate, the method comprising a step of:
using a sputtering method to continuously form the light semi-transmission film on the transparent substrate,
wherein dispersions of a phase angle and a transmittance of the light semi-transmission film among the plurality of halftone phase shift mask blanks are within ±2° and within ±4%, respectively.
(Constitution 3) A method of continuously manufacturing a plurality of photo mask blanks each having at least a thin film for forming a pattern on a transparent substrate, the method comprising a step of:
using a sputtering method to continuously form the thin film on the transparent substrate,
wherein the step of using the sputtering method to continuously form the thin film on the transparent substrate comprises steps of: successively subjecting a plu
Mitsui Hideaki
Nozawa Osamu
Cook Alex McFarron Manzo Cummings & Mehler, Ltd.
Hoya Corporation
VerSteeg Steven
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