Method for forming silicon nitride film having low leakage curre

Semiconductor device manufacturing: process – Coating of substrate containing semiconductor region or of... – Multiple layers

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438791, H01L 21318

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056630875

ABSTRACT:
The present invention provides a method for forming a silicon nitride film used for a capacitor dielectric film on a silicon substrate and a poly-silicon layer which comprises steps of forming a first thin silicon nitride film by a rapid thermal nitrogen process and forming a second silicon nitride film on the first thin silicon nitride film to a required thickness by LPCVD. In the LPCVD, a gas which reduces surface reactions is introduced to a growing surface of the silicon nitride film by a means different from a means supplying starting material gases of the silicon nitride film, so as to improve a break down voltage and leakage current of the capacitor silicon nitride film.

REFERENCES:
"The Effect of Surface Roughness of Si.sub.3 N.sub.4 Films on TDDB Characteristics of ONO Films", Tanaka et al, IEEE, 1992, pp. 31-36.
"Ultrathin Silicon Nitride Films Prepared by Combining Rapid Thermal Nitridation with Low-Pressure Chemical Vapor Deposition", Ando et al, Appl. Phys. Lett., vol. 59, No. 9, Aug. 26, 1991, pp. 1081-1083.

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