Method of producing non-volatile semiconductor memory device...

Semiconductor device manufacturing: process – Making field effect device having pair of active regions... – Having insulated gate

Reexamination Certificate

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Details

Other Related Categories

C438S301000, C438S304000

Type

Reexamination Certificate

Status

active

Patent number

06355525

Description

ABSTRACT:

BACKGROUND OF THE INVENTION
1. Field of the Invention
The present invention relates to a semiconductor memory device. More particularly, it relates to a non-volatile semiconductor memory device including memory cells each having a duplicate gate structure in which a floating gate and a control gate are stacked, such as an EPROM, an EEPROM or a flash memory, and to a method of producing the same.
2. Description of the Prior Art
FIGS. 1A through 1D
schematically illustrating steps of producing a memory cell in a flash memory according to prior art.
At the first step (see FIG.
1
A), an oxide film as an insulation film
2
for device isolation is deposited about 400 nm to 800 nm thick on a semiconductor substrate (e.g., a p-type silicon substrate) 1 by, for example, thermal oxidation, and an oxide film
3
to be a first gate insulation film is further deposited about 10 nm thick by thermal oxidation. Then, a polysilicon film
4
to be a floating gate is formed approximately 130 nm thick on the entire surface of the resultant structure, and phosphorus (P) or the like as an impurity is doped into the polysilicon film
4
. Then, an oxide film
5
to be a second gate insulation film is deposited about 20 nm thick by thermal oxidation after which a polysilicon film
6
to be a control gate is formed approximately 150 nm thick on the entire surface of the resultant structure, and phosphorus (P) or the like as an impurity is doped into the polysilicon film
6
.
At the next step (see FIG.
1
B), resist patterning (coating a resist on) of the control gate is carried out by using photolithography, and the polysilicon film
6
, the oxide film
5
, the polysilicon film
4
and the oxide film
3
are etched with the resist used as a mask. Then, the resist is removed. This completes a lamination structure in which the first gate insulation film
3
G, floating gate
4
G, the second gate insulation film
5
G and the control gate
6
G are stacked in order on the semiconductor substrate
1
as illustrated.
At the subsequent step (see FIG.
1
C), to make a source region of a high withstand voltage, as an impurity, phosphorus (P) or the like whose conductivity type is opposite to that of the semiconductor substrate
1
is lightly doped using photolithography, thereby forming an n-type diffusion layer
7
, and as another impurity, arsenic (As) or the like whose conductivity type is opposite to that of the semiconductor substrate
1
is heavily doped by photolithography, thereby forming an n-type diffusion layer (source region)
8
S and an n-type diffusion layer (drain region)
8
D. Next, an oxide film as an insulation film is grown about 200 nm thick on the entire surface of the resultant structure by chemical vapor deposition (CVD), then anisotropic dry etching is performed to form a side-wall insulation film
9
on the side walls of the lamination structure (
3
G,
4
G,
5
G and
6
G).
At the final step (see FIG.
1
D), after an interlayer insulation film LS is formed by CVD, contact holes which respectively reach the source region
8
S, the drain region
8
D and the control gate
6
G are formed, and electrode wires WS, WD and WG are so formed as to fill the individual contact holes. This completes the memory cell structure.
The write operation (programming) and erasing operation of a non-volatile semiconductor memory device which has memory cells that are fabricated in the above-described manner are implemented as follows. In the write mode, a voltage is applied between the control gate and the drain region in such a way as to generate a positive electric field therebetween. This causes hot electrons to be generated from the drain region. The electrons are injected into the floating gate to write information. In the erasure mode, a voltage is applied between the control gate and the source region in such a way as to generate a negative electric field therebetween, and electrons are drained into the source region from the floating gate through the oxide film (first gate insulation film) by the F-N (Fowler-Nordheim) tunnel current, thereby erasing information.
Since the write operation and erasing operation of a non-volatile semiconductor memory device are executed respectively by injection of electrons into the floating gate and draining of electrons from the floating gate, as mentioned above, their operation characteristics are influenced by the voltage that is applied to the floating gate. The floating gate voltage that affects the operation characteristics will now be described with reference to
FIG. 2
which shows the conceptual structure of a memory cell having a duplicate gate structure.
As shown in
FIG. 2
, assuming that the capacitance between the floating gate and the substrate is C
1
; the capacitance between the floating gate and the control gate is C
2
; the capacitance between the floating gate and the drain region is C
3
; the capacitance between the floating gate and the source region is C
4
; the drain voltage is V
D
; the source voltage is V
S
; the control gate voltage is V
CG
; the floating gate voltage is V
FG
; the area of the overlapping portion of the floating gate over the source region is S; an electric field which is applied to the oxide film (first gate insulation film) between the floating gate and the source region in the erasure mode is E
OX
; and the F-N tunnel current which flows into the source region from the floating gate in the erasure mode is I
FN
, the floating gate voltage in the write mode and the floating gate voltage and the F-N tunnel current I
FN
in the erasure mode are respectively expressed by following equations (1), (
2)
and (3).
V
FG(W)
={C
2
/(C
1
+C
2
+C
3
+C
4
)}V
CG
+{C
3
/(C
1
+C
2
+C
3
+C
4
)}V
D
  (1)
V
FG(E)
={C
2
/(C
1
+C
2
+C
3
+C
4
)}V
CG
+{C
4
/(C
1
+C
2
+C
3
+C
4
)}V
S
  (2)
I
FN
=A
FN
S E
OX
2
exp(B
FN
/E
OX
)  (3)
where A
FN
and B
FN
are constants.
Assuming that the control gate voltage V
CG
and the drain voltage V
D
are constant, the equation (1) shows that the floating gate voltage V
FG(W)
in the write mode becomes higher as the capacitances C
2
and C
3
get larger. The higher this floating gate voltage V
FG(W)
gets, the greater the amount of electrons to be injected into the floating gate becomes, so that the write time can be shortened. It is therefore preferable that the floating gate voltage V
FG(W)
is high. This requires that the capacitances C
2
and C
3
should be made large.
Likewise, assuming that the control gate voltage V
CG
and the source voltage V
S
are constant, it is apparent from the equation (2) that the floating gate voltage V
FG(E)
in the erasure mode becomes higher as the capacitance C
2
gets greater. The higher this floating gate voltage V
FG(E)
gets, the greater the amount of electrons to be drained from the floating gate becomes, allowing the erasure time to be shortened. It is therefore preferable that the floating gate voltage V
FG(E)
is high. This requires that the capacitance C
2
should be made large.
Also, assuming that the electric field E
OX
to be applied to the first gate insulation film is constant, it is apparent from the equation (3) that the larger the area S of the overlapping portion of the floating gate over the source region gets, the greater the F-N tunnel current I
FN
becomes, thereby permitting the erasure time to be shortened. It is thus preferable that the overlapping area S is large.
It should be understood from
FIG. 2
that the capacitance C
2
is proportional to the size of the opposing area of the floating gate to the control gate and is inversely proportional to the thickness of the second gate insulation film. The capacitance C
3
is proportional to the area of the floating gate that overlaps the drain region and is inversely proportional to the thickness of the first gate insulation film. The F-N tunnel current I
FN
is proportional to the area (S) of the floating gate that overlaps the source region.

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