Semiconductor device manufacturing: process – Making field effect device having pair of active regions... – Having insulated gate
Reexamination Certificate
1998-05-19
2001-09-04
Lee, Eddie (Department: 2815)
Semiconductor device manufacturing: process
Making field effect device having pair of active regions...
Having insulated gate
C438S396000, C438S502000, C438S800000
Reexamination Certificate
active
06284587
ABSTRACT:
BACKGROUND TO THE INVENTION
1. Field of the Invention
The present invention relates to a fabricating method for capacitor of a semiconductor device.
2. Description of the Related Art
The conventional method of building a capacitor into a semiconductor device has involved forming a dielectric film in the shape of a tantalum oxide, barium-strontium titanate or other oxide film on to a bottom electrode of polysilicon, metal or oxide conductive layer, then forming a top electrode of ruthenium, iridium or a similar substance.
When fabricating capacitors of this sort it is common to implement heat-treatment within oxygen, activated oxygen or ozone after formation of the dielectric film. This serves to increase dielectric constant by crystallizing the dielectric film, and to reduce current leakage by compensating oxygen deficit (cf. Japanese Laid-Open Publication No.82915/97).
FIG. 16
 is cross-section illustrating an example of the configuration of a conventional semiconductor device.
As 
FIG. 16
 shows, a device isolating silicon oxide film 
1602
 and a diffusion layer 
1603
 forming part of a MOS transistor or a similar device are formed on the surface of a silicon wafer 
1601
, followed by an interlayer insulator 
1604
. Then, after a contact hole 
1605
 has been formed in the film 
1604
, a bottom electrode 
1606
 is formed in the shape of an interlayer wiring film 
1606
a 
and conductive layer 
1606
b 
in polysilicon or a similar substance. Next, a tantalum oxide or other dielectric film 
1607
 is formed over the whole surface, and the capacitor is heat-treated in oxygen, activated oxygen or ozone as mentioned above. Finally, it is completed with the formation of a top electrode 
1608
 having a film of ruthenium, iridium or a similar substance which covers all the film 
1607
.
However, conventional capacitors such as those illustrated in 
FIG. 16
 suffer from the following defects.
As has been stated above, it has been common conventional practice to subject the capacitor to heat-treatment in an atmosphere of oxygen or the like after formation of the film 
1607
. As a result it sometimes happens that a silicon oxide layer 
1606
c 
is formed in the vicinity of the interfacial boundary between the films 
1606
a 
and 
1606
b
. This leads to the formation, in addition to the above mentioned capacitor, of another capacitor comprising the conductive films 
1606
a 
and 
1606
b 
along with the insulation layer 
1606
c
, so that two serially connected capacitors exist within the semiconductor device. Consequently, the total dielectric constant of the capacitors formed in such a semiconductor device falls below the intended level.
Moreover, it sometimes happens that during heat-treatment the layer 
1606
b 
oxidizes, thereby tending to increase the unevenness of the surface and resultant current leakage.
Conversely, the oxygen within the film 
1607
 may be released during heat-treatment, leading to oxygen deficit and consequent increased current leakage.
If the conductive layer 
1606
b 
is formed of a different material such as a metal or a conductive oxide, it may happen that a barrier layer (not shown in the drawing) forms between the films 
1606
b 
and 
1606
c
. In such cases, heat-treatment causes this barrier layer to oxidize into a dielectric layer, so that there is a risk of a capacitor being formed between the layers 
1606
b 
and 
1606
a
. The result again is that the total dielectric constant of the capacitors falls below the intended level.
Such defects combine to lower the yield of the semiconductor device, and result in increased costs.
SUMMARY OF THE INVENTION
It is an object of the present invention to provide a fabricating method for a semiconductor device whereby it is possible to prevent reduced yield caused during heat-treatment.
The fabricating method of a semiconductor device to which the present invention pertains comprises forming a laminated structure, having at least a first film for use in forming an oxidized dielectric film which contains an oxidizable substance for the purpose of forming an oxidized dielectric film, and a second film for use in supplying oxygen to said first film; and supplying oxygen from said second film to said first film by virtue of heat-treatment of said laminated structure within an atmosphere which does not contain oxygen.
The present invention allows the film for use in forming an oxidized dielectric film to oxidize as a result of heat-treatment within an atmosphere which does not contain oxygen.
REFERENCES:
patent: 4521951 (1985-06-01), Croset et al.
patent: 04171975a (1992-06-01), None
patent: 08330512a (1995-05-01), None
patent: 9-82915 (1997-03-01), None
Takehiro Shinobu
Yamauchi Satoshi
Yoshimaru Masaki
Brock II Paul E
Jones Volentine PLLC
Lee Eddie
OKI Electric Industry Co., Ltd.
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