ULSI MOS with high dielectric constant gate insulator

Active solid-state devices (e.g. – transistors – solid-state diode – Field effect device – Having insulated electrode

Reexamination Certificate

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C257S324000, C257S411000, C257S412000, C257SE21165

Reexamination Certificate

active

07042033

ABSTRACT:
MOS transistor formed on a semiconductor substrate of a first conductivity type and method of fabrication are provided. The device includes (a) an interfacial layer formed on the substrate; (b) a high dielectric constant layer covering the interfacial layer that comprises a material that is selected from the group consisting of Ta2O5, Ta2(O1−xNx)5wherein x ranges from greater than 0 to 0.6, a solid solution of (Ta2O5)r—(TiO2)1−rwherein r ranges from about 0.9 to less than 1, a solid solution (Ta2O5)s—(Al2O3)1−swherein s ranges from 0.9 to less than 1, a solid solution of (Ta2O5)t—(ZrO2)1−twherein t ranges from about 0.9 to less than 1, a solid solution of (Ta2O5)u—(HfO2)1−uwherein u ranges from about 0.9 to less than 1, and mixtures thereof wherein the interfacial layer separates the high dielectric constant layer from the substrate; (b) a gate electrode having a width of less than 0.3 micron covering the high dielectric constant layer; (d) first and second lightly doped regions of a second conductivity type disposed on respective areas of the substrate surface; (e) a source and drain regions of the second conductivity type; and (f) a pair of spacers formed adjacent to the gate electrode and formed on the high dielectric constant layer. The high dielectric layer can be subject to densification. The gate oxide material will significantly improve the performance of an MOS device by reducing or eliminating the current leakage associated with prior art devices.

REFERENCES:
patent: 3731163 (1973-05-01), Shukus
patent: 4670355 (1987-06-01), Matsudaira
patent: 4734340 (1988-03-01), Saito et al.
patent: 5091763 (1992-02-01), Sanchez
patent: 5189503 (1993-02-01), Suguro et al.
patent: 5200352 (1993-04-01), Pfiester
patent: 5292673 (1994-03-01), Shinriki et al.
patent: 5316977 (1994-05-01), Kunishima et al.
patent: 5322809 (1994-06-01), Moslehi
patent: 5439839 (1995-08-01), Jang
patent: 5596214 (1997-01-01), Endo
patent: 5677015 (1997-10-01), Hasegawa
patent: 5688724 (1997-11-01), Yoon et al.
patent: 5702972 (1997-12-01), Tsai et al.
patent: 5880508 (1999-03-01), Wu
patent: 5922673 (1999-07-01), Gluckman et al.
patent: 6087238 (2000-07-01), Gardner et al.
patent: 6107656 (2000-08-01), Igarashi
patent: 6458645 (2002-10-01), DeBoer et al.
patent: 0844647 (1998-05-01), None
patent: 60-107838 (1985-06-01), None
Alers, G.B. et al., “Nitrogen plasma annealing for low temperature Ta2O5films”, Applied Physics Letters, vol. 72, No. 11, 1308-1310, Mar. 16, 1998.
Campbell, S.A., et al., MOSFET Transistors Fabricated with High Permitivity TiO2Dielectrics, IEEE Transactions on Electron Device, vol. 44, No. 1, 104-109, Jan. 1997.
Cava, R.F. et al., “Enhancement of the dielectric constant of Ta2O5through substitution with TiO2”, Nature, vol. 377, 215-217, Sep. 21, 1995.
Chatterjee, A. et al., “Sub-100nm Gate Length Metal Gate NMOS Transistors Fabricated by a Replacement Gate Process”, IEEE, 1997.
Gan, J.-Y et al., “Dielectric property of (TiO2)x—(Ta2O5)1−xthin films”, Appl. Phys, Lett. 72 (3), Jan. 19, 1998, 332-334.
Hu, J.C. et al., “Feasibility of Using W/TiN as Metal Gate for conventional 0.13 μm CMOS Technology and Beyond”, IEEE, 1997.
Joshi, P.C., et al., “Structural and electrical properties of crystalline (1−x) Ta2O5—xAl2O3thin films fabricated by metalorganic solution deposition technique”, Apply. Phys. Lett. 71 (10), Sep. 8, 1997, 1341-1343.
Lo, G.Q. et al., Metal-oxide-semiconductor characteristics of chemical vapor deposited Ta2O5films, Appl. Phys. Lett. 60 (26), 3286-3288, Jun. 1992.
Meng, J.F., et al., “Raman Investigation on (Ta2O5)1−x(TiO2)xSystem at Different Temperatures and Pressures”, J. Phys. Chem Solids, vol. 58, No. 10, 1503-1506, 1997.
Momiyama, Y., et al., “Ultra-Thin Ta2O5/SiO2Gate Insulator with TiN Gate Technology for 0.1 μm MOSFETs”, 1997 Symposium on VLSI Technology digest of Technical Papers.
Properties of Metal Silicides, INSPEC emis datareviews series No. 14, 1995, Maex and Van Rossum Editors, pp 103-104.
Ting, C.Y., et al., “Gate Materials Consideration for Submicron CMOS”, Applied Surface Science 38 (1989) 416-428.
Ushiki T., et al., “High-Performance, Metal-Gate SOI CMOS Fabricated by Ultraclean, Low-Temperature Process Technologies”, SPIE, vol. 2875, pp 28-38, Aug. 1996.
Vogel, E.M., et al., “Modeled Tunnel Currents for High Dielectric constant Dielectrics”, IEEE Transactions on Electron Devices, vol. 45, No. 6, 1350-1355, Jun. 1998.
Pratt, I.H., “Thin-Film Dielectric Properties of R.F. Sputtered Oxides”,Solid State Technology, (Dec. 1969), vol. 12, No. 12, 49-57.
Reddy, P.K, et al., “Dielectric Properties of Tantalum Oxynitride Films”,Physica Status Solidi A, Jul. 1979, vol. 54, No. 1, pp. K63-K66.
Vlasov, Y.G. et al., “Analytical applications of pH-ISFETs”,Sensors and Actuators B, (Dec. 1992) vol. B10, No. 1, pp. 1-6.
Patent Abstracts of Japan, vol. 098, No. 11, Sep. 1998, JP 10 178170A.
Chinese Official Action dated Apr. 18, 2003 for Application No. 99808151.5.

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