Selective ruthenium deposition on copper materials

Semiconductor device manufacturing: process – Coating with electrically or thermally conductive material – To form ohmic contact to semiconductive material

Reexamination Certificate

Rate now

  [ 0.00 ] – not rated yet Voters 0   Comments 0

Details

C438S643000, C438S644000, C438S650000, C438S653000, C438S675000, C438S687000, C257SE21171, C257SE21577, C257SE21584, C257SE21586

Reexamination Certificate

active

07737028

ABSTRACT:
Embodiments of the invention provide processes for selectively forming a ruthenium-containing film on a copper surface over exposed dielectric surfaces. Thereafter, a copper bulk layer may be deposited on the ruthenium-containing film. In one embodiment, a method for forming layers on a substrate is provided which includes positioning a substrate within a processing chamber, wherein the substrate contains a copper-containing surface and a dielectric surface, exposing the substrate to a ruthenium precursor to selectively form a ruthenium-containing film over the copper-containing surface while leaving exposed the dielectric surface, and depositing a copper bulk layer over the ruthenium-containing film.

REFERENCES:
patent: 5372849 (1994-12-01), McCormick et al.
patent: 5962716 (1999-10-01), Uhlenbrock et al.
patent: 6063705 (2000-05-01), Vaartstra
patent: 6074945 (2000-06-01), Vaartstra et al.
patent: 6114557 (2000-09-01), Uhlenbrock et al.
patent: 6338991 (2002-01-01), Zhang et al.
patent: 6365502 (2002-04-01), Paranjpe et al.
patent: 6423619 (2002-07-01), Grant et al.
patent: 6440495 (2002-08-01), Wade et al.
patent: 6462367 (2002-10-01), Marsh et al.
patent: 6479100 (2002-11-01), Jin et al.
patent: 6482740 (2002-11-01), Soininen et al.
patent: 6498091 (2002-12-01), Chen et al.
patent: 6517616 (2003-02-01), Marsh et al.
patent: 6527855 (2003-03-01), DelaRosa et al.
patent: 6541067 (2003-04-01), Marsh et al.
patent: 6576778 (2003-06-01), Uhlenbrock et al.
patent: 6580111 (2003-06-01), Kim et al.
patent: 6596602 (2003-07-01), Iizuka et al.
patent: 6605735 (2003-08-01), Kawano et al.
patent: 6610568 (2003-08-01), Marsh et al.
patent: 6617634 (2003-09-01), Marsh et al.
patent: 6627995 (2003-09-01), Paranjpe et al.
patent: 6713373 (2004-03-01), Omstead
patent: 6737317 (2004-05-01), Marsh et al.
patent: 6743739 (2004-06-01), Shimamoto et al.
patent: 6744138 (2004-06-01), Marsh
patent: 6780758 (2004-08-01), Derderian et al.
patent: 6790773 (2004-09-01), Drewery et al.
patent: 6800542 (2004-10-01), Kim et al.
patent: 6800937 (2004-10-01), Marsh et al.
patent: 6824816 (2004-11-01), Aaltonen et al.
patent: 6861356 (2005-03-01), Matsuse et al.
patent: 6887795 (2005-05-01), Soininen et al.
patent: 6893915 (2005-05-01), Park et al.
patent: 7026714 (2006-04-01), Cunningham
patent: 7264846 (2007-09-01), Chang et al.
patent: 7265048 (2007-09-01), Chung et al.
patent: 7404985 (2008-07-01), Chang et al.
patent: 7429402 (2008-09-01), Gandikota et al.
patent: 7446032 (2008-11-01), Kailasam
patent: 7473634 (2009-01-01), Suzuki
patent: 7476618 (2009-01-01), Kilpela et al.
patent: 2001/0006838 (2001-07-01), Won et al.
patent: 2001/0054730 (2001-12-01), Kim et al.
patent: 2002/0000587 (2002-01-01), Kim et al.
patent: 2002/0004293 (2002-01-01), Soininen et al.
patent: 2002/0025627 (2002-02-01), Marsh et al.
patent: 2002/0028556 (2002-03-01), Marsh et al.
patent: 2002/0074577 (2002-06-01), Marsh et al.
patent: 2002/0076881 (2002-06-01), Marsh et al.
patent: 2002/0081381 (2002-06-01), DelaRosa et al.
patent: 2002/0102810 (2002-08-01), Iizuka et al.
patent: 2002/0121697 (2002-09-01), Marsh
patent: 2002/0125516 (2002-09-01), Marsh et al.
patent: 2002/0173054 (2002-11-01), Kim
patent: 2002/0197856 (2002-12-01), Matsuse et al.
patent: 2003/0096468 (2003-05-01), Soininen et al.
patent: 2003/0165615 (2003-09-01), Aaltonen et al.
patent: 2003/0212285 (2003-11-01), Uhlenbrock et al.
patent: 2004/0005753 (2004-01-01), Kostamo et al.
patent: 2004/0038529 (2004-02-01), Soininen et al.
patent: 2004/0105934 (2004-06-01), Chang et al.
patent: 2004/0113279 (2004-06-01), Chen et al.
patent: 2004/0211665 (2004-10-01), Yoon et al.
patent: 2004/0214354 (2004-10-01), Marsh et al.
patent: 2004/0241321 (2004-12-01), Ganguli et al.
patent: 2004/0266167 (2004-12-01), Dubin et al.
patent: 2005/0006799 (2005-01-01), Gregg et al.
patent: 2005/0081882 (2005-04-01), Greer et al.
patent: 2005/0085031 (2005-04-01), Lopatin et al.
patent: 2005/0124154 (2005-06-01), Park et al.
patent: 2005/0238808 (2005-10-01), Gatineau et al.
patent: 2006/0019494 (2006-01-01), Cao et al.
patent: 2006/0033678 (2006-02-01), Lubomirsky et al.
patent: 2006/0128150 (2006-06-01), Gandikota et al.
patent: 2006/0153973 (2006-07-01), Chang et al.
patent: 2006/0165892 (2006-07-01), Weidman
patent: 2006/0199372 (2006-09-01), Chung et al.
patent: 2006/0240187 (2006-10-01), Weidman
patent: 2006/0246699 (2006-11-01), Weidman et al.
patent: 2007/0004201 (2007-01-01), Lubomirsky et al.
patent: 2007/0054487 (2007-03-01), Ma et al.
patent: 2007/0077750 (2007-04-01), Ma et al.
patent: 2007/0099422 (2007-05-01), Wijekoon et al.
patent: 2007/0119370 (2007-05-01), Ma et al.
patent: 2007/0119371 (2007-05-01), Ma et al.
patent: 2007/0128862 (2007-06-01), Ma et al.
patent: 2007/0128863 (2007-06-01), Ma et al.
patent: 2007/0128864 (2007-06-01), Ma et al.
patent: 2007/0235059 (2007-10-01), Chu et al.
patent: 2008/0135914 (2008-06-01), Krishna et al.
patent: 2008/0274279 (2008-11-01), Chang et al.
patent: 2009/0065939 (2009-03-01), Suzuki
patent: 1293509 (2004-05-01), None
patent: 2001111000 (2001-04-01), None
patent: 2001237400 (2001-08-01), None
patent: WO-0188972 (2001-11-01), None
patent: WO-03056612 (2003-07-01), None
patent: WO-2005020317 (2005-03-01), None
Aaltonen “Atomic Layer Deposition of Noble Metal Thin Films,” Academic Dissertation presented at the Department of Chemistry of the University of Helsinki on Apr. 8, 2005, Helsinki, Finland, pp. 1-71.
Aaltonen, et al. “Atomic Layer Deposition of Ruthenium from RuCp2and Oxygen: Film Growth and Reaction Mechanism Studies,” Electrochemical Society Proceedings, vol. 2003-08, pp. 946-953.
Aaltonen, et al. “Atomic Layer Deposition of Ruthenium Thin Films from Ru(thd)3and Oxygen,” Chem. Vap. Deposition (2004), 10, No. 4, pp. 215-219.
Aaltonen, et al. “Ruthenium Thin Films Grown by Atomic Layer Deposition,” Chem. Vap. Deposition (2003), 9, No. 1, pp. 45-49.
Aoyama, et al. “Ruthenium Films Prepared by Liquid Source Chemical Vapor Deposition Using Bis-(ethylcyclopentadienyl)ruthenium,” Jpn. J. Appl. Phys. vol. 38 (1999), pp. L1134-L1136.
Dadgar, et al. “Growth of Ru doped semi-insulating InP by low pressure metalorganic chemical vapor deposition,” Journal of Crystal Growth 195 (1998), pp. 69-73.
Dadgar, et al. “Ruthenium: A superior compensator of InP,” Applied Physics Letters, vol. 73, No. 26, Dec. 28, 1998, American Institute of Physics, pp. 3878-3880.
Dey, et al. “Ruthenium films by digital chemical vapor deposition: Selectivity, nanostructure, and work function,” Applied Physics Letter, vol. 84, No. 9, Mar. 1, 2004, American Institute of Physics, pp. 1606-1608.
Goswami, et al. Transition Metals Show Promise as Copper Barriers, Semiconductor International, ATMI, San Jose—May 1, 2004.
Kwon, et al. “Atomic Layer Deposition of Ruthenium Thin Films for Copper Glue Layer,” Journal of the Electrochemical Society, 151 (2) (2004), pp. G109-G112.
Kwon, et al. “PEALD of a Ruthenium Adhesion Layer for Copper Interconnects,” Journal of the Electrochemical Society, 151 (12) (2004), pp. C753-C756.
Kwon, et al. “Plasma-Enhanced Atomic Layer Deposition of Ruthenium Thin Films,” Electrochemical and Solid-State Letters, 7 (4) (2004), pp. C46-C48.
Lashdaf, et al. “Deposition of palladium and ruthenium β-diketonates on alumina and silica supports in gas and liquid phase,” Applied Catalysis A: General 241 (2003), pp. 51-63.
Lim, et al. “Atomic layer deposition of transition metals,” Nature Materials, vol. 2, (Nov. 2003), pp. 749-754.
Meda, et al. “Chemical Vapor Deposition of Ruthenium Dioxide Thin Films From Bis(2,4-dimethylpentadienyl)Ruthenium,” Chemical Aspects of Electronic Ceramics Processing, Symposium Mater. Res. Soc., Warrendale, PA, USA, 1998, pp. 75-80, XP009050315, ISBN: 1-55899-400-9.
Shibutami, et al. “A Novel Ruthenium Precursor for MOCVD without Seed Ruthenium Layer,” TOSOH Research & Technology Review, vo

LandOfFree

Say what you really think

Search LandOfFree.com for the USA inventors and patents. Rate them and share your experience with other people.

Rating

Selective ruthenium deposition on copper materials does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Selective ruthenium deposition on copper materials, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Selective ruthenium deposition on copper materials will most certainly appreciate the feedback.

Rate now

     

Profile ID: LFUS-PAI-O-4247614

  Search
All data on this website is collected from public sources. Our data reflects the most accurate information available at the time of publication.