Selective etching of carbon-doped low-k dielectrics

Semiconductor device manufacturing: process – Chemical etching – Vapor phase etching

Reexamination Certificate

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C156S345340, C156S345380, C156S345440, C156S345450, C204S298340, C216S041000, C216S067000, C216S070000, C216S072000, C219S121400, C315S111210, C438S695000, C438S710000, C438S712000, C438S714000, C438S718000, C438S719000, C438S724000, C438S740000, C438S743000, C438S744000, C438S963000

Reexamination Certificate

active

10632873

ABSTRACT:
The present invention includes a process for selectively etching a low-k dielectric material formed on a substrate using a plasma of a gas mixture in a plasma etch chamber. The gas mixture comprises a fluorine-rich fluorocarbon or hydrofluorocarbon gas, a nitrogen-containing gas, and one or more additive gases, such as a hydrogen-rich hydrofluorocarbon gas, an inert gas and/or a carbon-oxygen gas. The process provides a low-k dielectric to a photoresist mask etching selectivity ratio greater than about 5:1, a low-k dielectric to a barrier/liner layer etching selectivity ratio greater about 10:1, and a low-k dielectric etch rate higher than about 4000 Å/min.

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