Reactive ion etch process including hydrogen radicals

Adhesive bonding and miscellaneous chemical manufacture – Delaminating processes adapted for specified product – Delaminating in preparation for post processing recycling step

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156657, 1566591, 156345, 252 791, B44C 122, C03C 1500, C03C 2506

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active

052425380

ABSTRACT:
The addition of a gaseous source of hydrogen radicals, such as hydrogen, ammonia or methane to oxide RIE etching chemistries, in amounts of from about 5 to about 20 percent by volume of the total gas flow, will increase the oxide etch rate while suppressing the polysilicon etch rate. This effect is more pronounced at lower wafer temperatures. This new process chemistry increases the oxide etch rate to greater than 5000 .ANG./min., improves the selectivity to polysilicon to greater than 25:1 and improves the selectivity to photoresist to greater than 6:1, without having a significant detrimental effect on the profile angle, the RIE lag and the etch rate uniformity. Selectivities of 50:1 have been achieved with less than 15% RIE lag using the chemistry CHF.sub.3, Ar, CF.sub.4 and NH.sub.3, with NH.sub.3 constituting 10 percent by volume of the gas flow.

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patent: 4324611 (1982-04-01), Vogel et al.
patent: 4668338 (1987-05-01), Maydan et al.
patent: 4687543 (1987-08-01), Bowker
patent: 4734157 (1988-03-01), Carbaugh et al.
patent: 4857140 (1989-08-01), Loewenstein
patent: 5021121 (1991-06-01), Groechel et al.

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