Radical oxidation and/or nitridation during metal oxide...

Semiconductor device manufacturing: process – Making field effect device having pair of active regions... – Having insulated gate

Reexamination Certificate

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C438S216000, C438S785000, C438S104000

Reexamination Certificate

active

06884685

ABSTRACT:
A metal oxide high-k dielectric is deposited on a semiconductor wafer in a manner that reduces dangling bonds in the dielectric without significantly thickening interfacial oxide thickness. A metal oxide precursor and radical oxygen and/or radical nitrogen are co-flowed over the semiconductor wafer to form the high-k dielectric. The radicals bond to dangling bonds of the metal of the metal oxide during the deposition process that is performed at the regular deposition temperature of less than about 400 degrees Celsius. The radical oxygen and radical nitrogen do not require the higher temperatures generally required in an anneal in order to attach to the dangling bonds of the metal. Thus, a high temperature post deposition anneal, which tends to cause interfacial oxide growth, is not required. The dielectric is of higher quality than is typical because the dangling bonds are removed during deposition rather than after the dielectric has been deposited.

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A. L. P. Rotondaro, et al., “Advanced CMOS Transistors with a Novel HfSiON Gate Dielectric,”2002 Symposium on VLSI Technology Digest of Technical Papers, Section 15.2.
Yuji Saito, et al., “Advantage of Radical Oxidation for Improving Reliability of Ultra-Thin Gate Oxide,”2002 Symposium on VLSI Technology Digest of Technical Papers.
M. Togo, et al., “Low-Leakage and Highly-Reliable 1.5 nm SiON Gate-Dielectric Using Radical Oxynitridation for Sub-0.1 μm CMOS,”2000 Symposium on VLSI Technology Digest of Technical Papers.

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