Process for preventing corrosion of aluminum bonding pads after

Semiconductor device manufacturing: process – Coating with electrically or thermally conductive material – To form ohmic contact to semiconductive material

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438695, 438696, 438963, 438976, 438637, 438712, 438724, 438723, 438694, 438680, H01L 2144

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059306645

ABSTRACT:
A method for etching access opening to aluminum alloy wire bonding pads of integrated circuit chips is described wherein a polymer layer is in-situ deposited into the opening after the bonding pad has been exposed by dry etching of a passivation layer. The passivation layer, is first etched with fluorocarbon etchants and then a TiN ARC layer is removed from over the aluminum bonding pad with etchants which may contain chlorine either as etch components or as a contaminant in an etchant such as SF.sub.6 non-volatile chlorine containing residues including AlCl.sub.3 and trapped Cl.sub.2, are left behind after the ARC layer has been removed. These cause corrosion of the bonding pad when exposed to atmospheric moisture. The polymer layer deposited immediately after the pad surface is exposed by the etchant, provides a temporary seal over the aluminum bonding pad, protecting it from exposure to moisture during subsequent processing steps.

REFERENCES:
patent: 5447598 (1995-09-01), Mihara et al.
patent: 5533635 (1996-07-01), Man
patent: 5540812 (1996-07-01), Kadomura
S Wolf et al. "Silicon Processing For The VLSI Era-vol. 1", Lattice Press. Sunset Beach, CA, 1986, p. 563.
Wolf etal., "Silicon Processing For The VLSI Era-vol. 1", Lattice Press, SUnset CA, 1986, p. 563-564.

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