Process for ozone bleaching of oxygen delignified pulp while con

Paper making and fiber liberation – Processes of chemical liberation – recovery or purification... – With regeneration – reclamation – reuse – recycling or...

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162 56, 162 57, 162 65, 162 90, D21C 9147, D21C 9153, D21C 918

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054095700

ABSTRACT:
A process for delignifying and bleaching a lignocellulosic pulp without the use of elemental chlorine or chlorine-containing compounds by oxygen delignifying the pulp to a K No. of about 14 or less and a viscosity of greater than about 10 cps and thereafter further delignifying the partially delignified pulp by lifting, displacing and tossing the pulp in a radial direction while advancing it in an axial direction in a plug flow-like manner with an effective amount of ozone for a sufficient time to obtain a substantially delignified pulp having a K No. of about 6 or less, a viscosity of at least about 7 cps and a GE brightness of at least about 35. The substantially delignified pulp may then be brightened to a final product having a GE brightness of at least about 75, or alternately up to about 83 or more by contacting the ozonated pulp with chlorine dioxide or a peroxide compound. Because of the absence of elemental chlorine in this sequence, filtrate from all stages but the chlorine dioxide stage (if used) can be recovered without sewering. Major environmental improvements are thus achieved.

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