Radiation imagery chemistry: process – composition – or product th – Imaging affecting physical property of radiation sensitive... – Radiation sensitive composition or product or process of making
Patent
1995-12-08
1997-03-18
McPherson, John A.
Radiation imagery chemistry: process, composition, or product th
Imaging affecting physical property of radiation sensitive...
Radiation sensitive composition or product or process of making
430326, 430914, 430921, G03C 173
Patent
active
056121709
ABSTRACT:
A positive resist composition based on a silicone polymer contains a photo acid generator which will decompose to generate an acid upon exposure to radiation. The silicone polymer includes hydroxybenzyl units wherein some OH groups are replaced by t-butoxycarbonyl, t-butoxycarbonylmethyl, trimethylsilyl or tetrahydropyranyl groups. In a first form, the photo acid generator is a specific onium salt having at least one phenyl group with a t-alkoxy, t-butoxycarbonyloxy or t-butoxycarbonylmethoxy substituent. In a second form, the composition further contains a nitrogenous compound. In a third form, the composition further contains a dissolution inhibitor in the form of a specific silicone compound. The composition is sensitive to high energy radiation and has high sensitivity and resolution.
REFERENCES:
patent: 5318876 (1994-06-01), Schwalm et al.
Abstract of JP 6-118651, Tanaka et al. (Apr. 1994).
Abstract of EP 520,265, Binder et al. (Jun. 1992).
Ishihara Toshinobu
Kawai Yoshio
Nakamura Jiro
Takemura Katsuya
Tanaka Akinobu
McPherson John A.
Nippon Telegraph and Telephone Company
Shin-Etsu Chemical Co. , Ltd.
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