Polymeric self-assembled mono- and multilayers and their use in

Radiation imagery chemistry: process – composition – or product th – Imaging affecting physical property of radiation sensitive... – Forming nonplanar surface

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430323, 430324, 1562722, 1562755, 428420, G03C 500, B32B 3100, B32B 704

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active

058857532

ABSTRACT:
A self-assembled multilayer and in particular polymeric self-assembled multilayer can be effectively produced from two or more self-assembled monolayers on a substrate where each of the self-assembled monolayers is produced for a block containing a first functional group and a second functional group where the second functional group is reacted with the first functional group. The production of polymerizable, self-assembled mono- and multi-layers from, e.g., blocks containing at least two acetylene groups and/or polymerizable end groups, is also provided. The polymerized mono- or multilayer can be employed in a variety of applications including photolithography.

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M. Itoh, "Preparation and Evaluation of Two Dimensional Polymer Films by Chemical Modification of an Alkanethiol Self-Assembled . . . ", J. Electrochem. Soc. Nov. 1995, vol. 142, No. 11, pp. 3696-3703.
T. Kim et al., "Polymeric Self-Assembling Monolayers" 1. Tetrahedron Letters, 1994, vol. 35, No. 51, pp. 9501-9504.
T. Kim et al., "Polymeric Self-Assembled Monolayers", 2. J. Am. Chem. Soc. 1995, vol. 117, pp. 3963-3967.
D. N. Batchelder, "Self-Assembled Monolayers containing Polydiacetylenes", J. Am. Chem. Soc. 1994, vol. 116, pp. 1050-1053.
Dubois et al., Annu.Rev.Phys.Chem., vol. 43, 1992, 437-463.

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