Radiation imagery chemistry: process – composition – or product th – Imaging affecting physical property of radiation sensitive... – Light scattering or refractive index image formation
Reexamination Certificate
2000-12-01
2003-11-25
McPherson, John A. (Department: 1756)
Radiation imagery chemistry: process, composition, or product th
Imaging affecting physical property of radiation sensitive...
Light scattering or refractive index image formation
C430S321000
Reexamination Certificate
active
06653051
ABSTRACT:
BACKGROUND OF THE INVENTION
The present invention relates to the application of the photorefractive effect to the fabrication of optical devices based on oxynitride glass, and more particularly, to photoinduced Bragg gratings in oxynitride optical fibers.
Reflection gratings are often implemented as waveguides which have a path region having a modulated refractive index. The waveguiding structure is often in the form of a fiber. The modulation preferably takes the form of alternate regions of higher and lower refractive index. These periodic variations in refractive index act as a Bragg grating, and they selectively reflect light having a wavelength of twice the spacing. Such gratings can be used to filter, to define laser cavities and as components in multiplexers and demultiplexers.
Photoinduced Bragg gratings have been made in a variety of ways. One approach, which is disclosed in U.S. Pat. No. 4,725,110, is to direct two interfering beams of ultraviolet radiation through the cladding of an optical fiber to form an interference pattern along the germania-doped glass core. Other techniques involve subjecting regions of a fiber core to ultraviolet radiation through an amplitude mask or a phase mask. U.S. Pat. No. 5,287,427 teaches that the refractive index effect is enhanced by exposing that part of the glass that is to be subjected to actinic radiation to hydrogen or deuterium.
Germania-doped silica has shown the greatest refractive index change (&Dgr;n) after being subjected to actinic radiation. For various reasons attempts have been made to make gratings from photosensitive materials other than germania, a relatively scarce, expensive constituent. An object of the invention is to provide reflective gratings that are formed from commonly occurring, inexpensive materials. Another object of the invention is to provide a germania-free glass from which reflection gratings can be made.
Reflective gratings have been made from other UV sensitive oxides that are less effective than germania. It is disclosed in WO 94/00784 that photoinduced ratings can be made from B
2
O
3
in combination with SiO
2
or GeO
2
. The publication, Kitagawa et al., OFC Vol.4 of 1994 OSA Technical Digest Series, paper PD-17 teaches that gratings can be made by pulsing optical fibers having P
2
O
5
—SiO
2
cores with 193 nm radiation. U.S. Pat. No. 5,478,371 teaches a technique for forming gratings in P
2
O
5
doped optical fiber with 248 nm radiation. Such photosensitive oxides can be used alone or in combination with other photosensitive oxides such as germania. A further object of the invention is to provide a photosensitive material that can be used in combination with other photosensitive materials to form reflection gratings.
SUMMARY OF THE INVENTION
Briefly, the present invention relates to an optical device comprising a nitrogen-doped silica glass region having a pattern of photo-altered refractive index variations. The pattern of refractive index variations preferably takes the form of alternate regions of higher and lower refractive index, the period of which is such that the pattern constitutes a reflection grating. The nitrogen-doped silica glass region can be the core region of an optical waveguide, the core region being at least partially surrounded by a cladding, the optical waveguide comprising a portion wherein the core region has a refractive index that varies in a longitudinal direction, the index varying such that the portion of the waveguide reflects radiation of a predetermined wavelength propagating longitudinally in the waveguide. The optical waveguide can be an optical fiber or a planar device.
The present invention also relates to a method of making an optical component. The method comprises (a) providing a body at least a portion of which comprises silicon oxynitride glass, and (b) exposing at least a part of the portion to actinic radiation such that the refractive index of the exposed part is changed. The change in refractive index of the irradiated region is enhanced by impregnating the irradiated region with an atmosphere comprising hydrogen or deuterium. To make a reflective grating, the irradiated region is exposed to a modulated intensity of actinic radiation whereby the refractive index thereof is modulated to reproduce the intensity pattern of the radiation.
REFERENCES:
patent: 3999835 (1976-12-01), Newns et al.
patent: 4165223 (1979-08-01), Powers
patent: 4203744 (1980-05-01), Schultz et al.
patent: 4402720 (1983-09-01), Edahiro et al.
patent: 4557561 (1985-12-01), Schneider et al.
patent: 4725110 (1988-02-01), Glenn et al.
patent: 4807950 (1989-02-01), Glenn et al.
patent: 5152819 (1992-10-01), Blackwell et al.
patent: 5287427 (1994-02-01), Atkins et al.
patent: 5416863 (1995-05-01), Vengsarkar
patent: 5455211 (1995-10-01), McMillan et al.
patent: 5478371 (1995-12-01), Lemaire et al.
patent: 5518970 (1996-05-01), McMillan et al.
patent: 5635310 (1997-06-01), Kudo et al.
patent: 5675691 (1997-10-01), Edlinger et al.
patent: 0 569 182 (1993-11-01), None
patent: 0 622 343 (1994-11-01), None
patent: 0 784 217 (1997-07-01), None
patent: 63085023 (1988-04-01), None
patent: 7244210 (1995-09-01), None
patent: 2010775 (1994-04-01), None
patent: WO 94/00784 (1994-01-01), None
patent: WO 98/28643 (1997-06-01), None
patent: WO 97/23426 (1997-07-01), None
Dianov et al., “Grating Formation in a Nitrogen-Doped-Silica-Core Fibre”, Feb. 1997.*
Bruno, F. et al.,Plasma-enhanced chemical vapor deposition of low-loss SiON optical waveguides at 1.55-&mgr;m wavelength, Applied Optics, vol. 30, No. 31, pp. 4560-4564, 1991.
Bubnov et al.,Low-Loss Silicon Oxynitride Optical Fibres, Proc. 21stEur. Conf. on Opt. Comm. (EEOC '95-Brussels), pp. 329-332.
Bufetov et al.,Ultraviolet-light generation in nitrogen-doped silica fiber, Optics letters, vol. 22, No. 18, Sep. 15, 1997, pp. 1394-1396.
Dianov et al.,Highly photosensitive nitrogen-doped germanosilicate fibre for index grating writing, Electronics Letters, Jul. 17, 1997, vol. 33, No. 15, pp. 1334-1346.
Dianov et al.,Low-Hydrogen Silicon Oxynitride Optical Fibers Prepared by SPCVD, Journal of Lightwave Technology, 1995, LT13, (7), pp. 1471-1474.
Dianov et al.,Highly Photosensitive Germanosilicate fibre Codoped with Nitrogen, OSA Technical Digest, vol. 17 (1997), pp. 153-155.
Dianov et al.,Low-Loss nitrogen-doped silica fibers: the prospects for applications in radiation environments, OFC '96 Technical Digest, pp. 61-62.
Dianov et al.,Grating Formation in a Nitrogen-Doped-Silica-Core Fibre, OFC 97, Feb. 16-21, 1997.
Dianov et al.,Nitrogen doped silica core fibres: A new type of radiation-resistant fibre, Electronics Letters, Aug. 17, 1995, vol. 31, No. 17, pp. 1490-1491.
Dianov et al.,UV absorption and luminescence in silicon oxynitride prepared by hydrogen-free SPCVD-process, Optical Materials 5 (Mar. 1996), pp. 169-173.
Juma, Salim,Fibre gratings reinforce the bandwidth explosion, OLE—Opto & Laser Europe, Oct. 1996.
Karpov et al.,Ultra-Thermostable Long-Period Gratings Induced in Nitrogen-Doped Silica Fiber, Fiber Optics Research Center at the General Physica Institute of the Russian Academy of Sciences, 38 Vavilov St., Moscow 117942, Russia.
Kitagawa et al., OFC, vol. 4 of 1994 OSA Technical Digest Series, paper PD-17.
Storgaard-Larsen, T.,Nitrogen Doped Germania Glasses with Enhanced Optical and Mechanical Properties, J. Electrochem. Soc., vol. 144, No. 6, Jun. 1997, pp. 2137-2142.
Storgaard-Larsen, T.,Opto-Mechanical Accelerometer based on Strain Sensing by a Bragg Grating in a Planar Waveguide, Lyngby, Denmark: Mikroelektronik Centret 1996.
Borrelli Nicholas Francis
Cook Thomas Allen
DeLiso Evelyn McGee
Modavis Robert Adam
Corning Incorporated
McPherson John A.
Oliver Kevin A.
Sinort Svetlana Z.
LandOfFree
Photoinduced grating in oxynitride glass does not yet have a rating. At this time, there are no reviews or comments for this patent.
If you have personal experience with Photoinduced grating in oxynitride glass, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Photoinduced grating in oxynitride glass will most certainly appreciate the feedback.
Profile ID: LFUS-PAI-O-3114366