Phase-changeable memory devices having phase-changeable...

Active solid-state devices (e.g. – transistors – solid-state diode – Field effect device – Having insulated electrode

Reexamination Certificate

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C257S003000, C257S528000, C257S529000, C438S095000, C438S215000

Reexamination Certificate

active

06806528

ABSTRACT:

RELATED APPLICATION
This application claims priority from Korean Patent Application No. 2002-52728 filed on Sep. 3, 2002 in the Korean Intellectual Property Office, the disclosure of which is incorporated herein in its entirety by reference.
FIELD OF THE INVENTION
The present invention relates to semiconductor memory devices and methods of fabrication therefor, and more particularly, to phase-changeable memory devices and methods of fabrication therefor.
BACKGROUND OF THE INVENTION
Semiconductor memory devices can be categorized as either volatile memory devices or nonvolatile memory devices according to whether or not data is retained when power supplies are interrupted. The volatile memory devices may be classified into a dynamic random access memory (DRAM) and a static random access memory (SRAM). The nonvolatile memory devices include flash memory devices. These memory devices represent a logic value, such as “0” or “1,” based on stored charge. Because a periodic refresh operation is typically needed for such devices, a DRAM may require a high charge storage capacitance. Consequently, there have been attempts to increase a surface area of a capacitor electrode to increase storage capacitance. However, an increase in the surface area of the capacitor electrode can interfere with an increase in integration of the DRAM.
A typical flash memory device has gate patterns including a gate insulating layer, a floating gate, a dielectric layer, and a control gate, which are sequentially stacked on a semiconductor substrate. To write and erase data, a method of tunneling charges through the gate insulating layer is used at a voltage that is higher than the normal power supply voltage. Accordingly, flash memory devices typically require a booster circuit in order to produce the voltage for erase and write operations.
As memory devices become highly integrated, many efforts have been underway to develop a new memory device having nonvolatile and random access characteristics, and a simple structure. Phase-changeable memory devices are one type of such memory devices. A typical phase-changeable memory device has a cell made of a phase-changeable material. Depending on a provided current density (i.e., Joule heating), the phase-changeable material can be electrically switched between amorphous and crystalline states and/or between variously resistive crystalline states.
FIG. 1
is a graph showing a method of programming and erasing a phase-changeable memory cell. Here, a horizontal axis represents time (T) and a vertical axis represents temperature (TMP: ° C.) applied to the phase-changeable material cell. The phase-changeable material is heated at a temperature that is higher than a melting temperature Tm during a relatively short first time T1. Next, the phase-changeable material is rapidly quenched. In this case, the phase-changeable material may be changed into the amorphous state (curve
1
). During a second time T2 that is longer than the first time T1, the phase-changeable material is heated at a temperature that is lower than the melting temperature Tm and is higher than a crystallization temperature Tc. Next, the phase-changeable material is quenched. In this case, the phase-changeable material is changed into the crystalline state (curve
2
). The resistivity of the phase-changeable material with the amorphous state is higher than that of the phase-changeable material with the crystalline state. Accordingly, currents flowing through the phase-changeable material may be detected in a read mode, and it is possible to discriminate whether information stored in the phase-changeable memory cell has a logic value of “1” or “0”. Generally, a chalcogenide material is used as the phase-changeable material, in particular, a compound (hereinafter a “GST layer”) including germanium (Ge), stibium (Sb), and tellurium (Te).
As described above, heat is typically needed in order to switch the state of the phase-changeable material. In the typical phase-changeable memory device, if currents of a high density flow through an area contacting the phase-changeable material, a crystallization state of the phase-changeable material at a contact area is varied. The smaller the contact area is, the lower the current density for changing the state of the phase-changeable material.
FIG. 2
is a cross-sectional view for explaining a typical phase-changeable memory device structure, which schematically shows a phase-changeable memory cell. Referring to
FIG. 2
, the typical phase-changeable memory device includes a lower conductive pattern
10
, a phase-changeable material pattern
16
and an upper conductive pattern
18
. The phase-changeable material pattern
16
is electrically connected to the lower conductive pattern
10
through a contact plug
14
formed in an insulating layer
12
. The insulating layer
12
is disposed on the lower conductive pattern
10
. The upper conductive pattern
18
is formed on the phase-changeable material pattern
16
. In the typical phase-changeable memory device, if currents flow between the lower conductive pattern
10
and the upper conductive pattern
18
, the crystallization state of the phase-changeable material varies in accordance with a pulse (i.e., heat) of the currents flowing through an area (hereinafter referred to as “active contact area”)
20
where the contact plug
14
is in contact with the phase-changeable material pattern
16
. The heat (i.e., energy) required to change the state of the phase-changeable material is directly affected by the active contact area
20
where the phase-changeable material pattern
16
is in contact with the contact plug
14
. Preferably, the active contact area
20
should be made as small as possible.
However, because the lower conductive pattern
10
is connected to the phase-changeable material pattern
16
through the contact plug
14
, a size of the active contact area
20
may be limited by a photolithography resolution for the contact hole, i.e., the size of the active contact area
20
generally cannot be reduced beyond the photolithography resolution. Furthermore, it may be difficult to form such contact holes uniformly in the memory device, which can result in variance in current flow for changing the state of the phase-changeable material for each contact area. Thus, mis-operation in read mode can easily occur. Also, because only one active contact area
20
is formed at the area that is in contact with the contact plug
14
, a resistance variation resulting from the variation of the crystallization state is small.
SUMMARY OF THE INVENTION
According to some embodiments of the present invention, a phase-changeable memory device comprises a substrate and an access transistor formed in and/or on the substrate. Laterally spaced apart first and second conductive patterns are disposed on the substrate and have opposing sidewalls. A conductor electrically connects the first conductive region to a source/drain region of the access transistor. A phase-changeable material region is disposed between the first and second conductive patterns and contacts the opposing sidewalls of the first and second conductive patterns.
In some embodiments, the access transistor comprises first and second source/drain regions in the substrate and a gate electrode disposed on the substrate between the first and second source drain regions. The memory device further comprises an insulating layer disposed on the substrate and overlying the gate electrode and the first and second source/drain regions. The first and second conductive patterns are disposed on the insulating layer, and the conductor passes through the insulating layer and connects the first conductive pattern to the first source/drain region. The phase-changeable material layer is disposed on the insulating layer between the first and second conductive regions. The first and second conductive patterns may overlie respective ones of the first and second source/drain regions, and the phase-changeable material region may overlie the gate electrode.
According to further aspects, the co

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