Nanoparticle and nanoparticle composite

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

Reexamination Certificate

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C556S400000

Reexamination Certificate

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07825283

ABSTRACT:
A nanoparticle includes a chain oligomer section having a hydrophilic group and fluoroalkyl groups respectively at its opposite terminals, a three-dimensional silica network section, and an organic chain having fluorine or silicon, and is represented by the following formula (1):where R′ is independent H or independent alkyl group; X is the hydrophilic group and is independent OH group, independent NCO group, independent NH2group or the like; RFis the fluoroalkyl group having a carbon number of 2 to 10 and a molecular weight of 119 to 1000; 3D-SN is the three-dimensional silica network section; B is independent O, independent O═C—O or the like; E is O, O═C—O, NH—C═O or the like; G is [(CH2O)1—[Si(CH3)2O]k—(CH2O)1] or the like.

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patent: 2007/0172673 (2007-07-01), Becker et al.
Sawada et al., {Preparation of novel fluoroalkyl end-capped oligomers/silica hybrid nanoparticles-encapsulation of a variety of guest molecules into fluorinated nanoparticles, Colloid & Polymer Science, vol. 284, No. 5, Feb. 2006, 551-555}.
H. Sawada et al., “Solubilization of fullerene into ionic liquids by the use of fluoroalkyl end-capped oligomers,” Polymers for Advanced Technologies, vol. 16, 2005, pp. 655-658.
H. Sawada et al., “Solubilization of fullerene into water with fluoroalkyl end-capped amphiphilic oligomers—novel fluorescence properties,” Journal of Colloid and Interface Science 263 (2003), pp. 1-3.
H. Sawada, “Construction of Nano-level Structure-controlled Fluorine-based Molecule Aggregate and Coating Surface Improvement,” Science Council of Japan, 11thInterface Symposium, (2004), pp. 63-85.
U.S. Appl. No. 11/715,495, filed Mar. 8, 2007, Yaegashi et al.

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