Methods for improving sheet resistance of silicide layer...

Semiconductor device manufacturing: process – Coating with electrically or thermally conductive material – To form ohmic contact to semiconductive material

Reexamination Certificate

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Reexamination Certificate

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06838381

ABSTRACT:
A method of manufacturing a semiconductor device is provided. A nickel silicide layer (e.g., NiSi) is formed on a substrate. Next, a hydrogen plasma treatment may be performed on the silicide layer, which may induce the formation of metal/silicon hydride bonds in the silicide layer. An etch stop layer is formed over the silicide layer. A dielectric layer is formed over the etch stop layer. An opening is formed in the dielectric layer. A portion of the etch stop layer is etched away at the opening to expose at least a portion of the silicide layer therebeneath. The etch chemistry mixture used during the etching step preferably includes hydrogen gas. The change in sheet resistance for the exposed silicide layer portion at the opening after the etching step, as compared to before the etching step, is preferably not greater than about 0.10 ohms/square.

REFERENCES:
patent: 6265271 (2001-07-01), Thei et al.
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Totir, G.G., et al.X-Ray Photoelectron Spectroscopy and Morphological Studies of Polycrystalline Nickel Surfaces Exposed to Anhydrous HF, Journal of the Electrochemical Society, vol. 147, No. 11 (2000) pp. 4212-4216.
Gambino, J.P., et al.Invited Review-Silicides and Ohmic Contacts, Materials Chemistry and Physics, vol. 52 (1998) pp. 99-146.
Ohguro, T., et al.Analysis of Resistance Behavior in Ti- and Ni-Salicided Polysilicon Films, IEEE Transactions on Electron Devices, vol. 41, No. 12 (Dec. 1994) pp. 2305-2317.
Grunthaner, P.J., et al.Oxygen Impurity effects at metal/silicide interaces: Formation of silicon oxide and suboxides in the Ni/Si system, J. Vac. Sci. Technol., vol. 19, No. 3 (Sep./Oct. 1981) pp. 641-648.
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