Methods for determining organic component concentrations in...

Electrolysis: processes – compositions used therein – and methods – Electrolytic coating – Involving measuring – analyzing – or testing

Reexamination Certificate

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C205S083000, C205S101000, C205S296000, C205S787000

Reexamination Certificate

active

06984299

ABSTRACT:
The present invention relates to a method and apparatus for determining organic additive concentrations in a sample electrolytic solution, preferably a copper electroplating solution, by measuring the double layer capacitance of a measuring electrode in such sample solution. Specifically, the present invention utilizes the correlation between double layer capacitance and the organic additive concentration for concentration mapping, based on the double layer capacitance measured for the sample electrolytic solution.

REFERENCES:
patent: 4707378 (1987-11-01), McBride et al.
patent: 4812210 (1989-03-01), Bonivert et al.
patent: 6572753 (2003-06-01), Chalyt et al.
Keith B. Oldham and Jan C. Myland “Fundamentals of Electrochemical Science” Academic Press, San Diego, 1994, p. 329-330.
Allen J. Bard, “Electrochemical Methods, Fundamentals and Applications” 2ndedition, John Wiley & Son, New York, 2001, p. 15.
Yonghui Liu “Testing Technology of Electrochemistry”, Beijing, 1987, p. 159 (English relevance attached).
Alexander Milchev and Irene Montenegro, J. Electroanal. Chem., 333 (1992), pp. 93-102.

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