Method of plasma enhanced atomic layer deposition of TaC and...

Semiconductor device manufacturing: process – Coating with electrically or thermally conductive material – To form ohmic contact to semiconductive material

Reexamination Certificate

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C438S618000, C438S648000, C438S680000, C257SE21170, C257SE21171, C257SE21168

Reexamination Certificate

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07407876

ABSTRACT:
A method for processing a substrate for forming TaC and TaCN films having good adhesion to Cu. The method includes disposing the substrate in a process chamber of a plasma enhanced atomic layer deposition (PEALD) system configured to perform a PEALD process, and depositing a TaC or TaCN film on the substrate using the PEALD process. The PEALD process includes (a) exposing the substrate to a first process material containing tantalum, (b) exposing the substrate to a second process material containing a plasma excited reducing agent, (c) repeating steps (a) (b) a predetermined number of times, (d) exposing the substrate to plasma excited Argon, and (e) repeating steps (c) and (d) until the TaC or TaCN film has a desired thickness. Preferably, purging of the process chamber is performed after one or more of the exposing steps.

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Kim, J.Y., et al., “Basic characteristics of TaN films deposited by using the remote plasma enhanced atomic layer deposition method,” Journal of the Korean Physical Society, Oct. 2004, vol. 45, No. 4, pp. 1069-1073.
Park, J.S. et al., “Plasma-enhanced atomic layer deposition of tantalum nitrides using hydrogen radicals as a reducing agent,” Electrochemical and Solid-State Letters, 2001, vol. 4, No. 4, pp. C17-C19.

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