Method of manufacturing an insulating film containing hafnium

Semiconductor device manufacturing: process – Coating of substrate containing semiconductor region or of... – Insulative material deposited upon semiconductive substrate

Reexamination Certificate

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C438S287000, C438S785000, C257SE21010

Reexamination Certificate

active

07838439

ABSTRACT:
A stacked film has an insulating film containing hafnium formed above a silicon layer and a polysilicon layer formed on the insulating film. The stacked film is heated in an atmosphere containing oxygen and nitrogen and having the total pressure approximately equal to a partial pressure of the nitrogen.

REFERENCES:
patent: 2005/0070123 (2005-03-01), Hirano
patent: 2005/0124121 (2005-06-01), Rotondaro et al.
H. Takahashi et al, “Chemical reaction at the interface between polycrystalline Si electrodes and HfO2/ Si gate dielectrics by annealing in ultrahigh vacuum”, 2005 American Institute of Physics, Applied Physics Letters 87, 012903(2005), published online Jun. 29, 2005, pp. 1-3.
S. Toyoda et al, “Annealing-temperature dependence: Mechanism of Hf silicidation in HfO2gate insulators on Si by core-level photoemission spectroscopy”, 2006 American lnsitiute of Physics, Journal of Applied Physics 99, 014901 (2006), Published online Jan. 3, 2006, pp. 1-5.
S. Toyoda et al, “Crystallization in HfO2gate insulators with in situ annealing studied by valence-band photoemission and x-ray absorption spectroscopy”, 2005 American Institute of Physics, Journal of Applied Physics 97, 014507(2005), Published online May 5, 2005. pp. 1-4.

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