Method of forming a storage capacitor

Semiconductor device manufacturing: process – Making field effect device having pair of active regions... – Having insulated gate

Reexamination Certificate

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C438S254000

Reexamination Certificate

active

06200845

ABSTRACT:

BACKGROUND OF THE INVENTION
The present invention relates to a method of forming a storage capacitor, and more particularly to a method of forming a storage capacitor used in a semiconductor memory device such as a dynamic random access memory.
In the semiconductor memory device such as the dynamic random access memory, staked capacitors are used to ensure a large capacity with realizing a high density integration of the semiconductor memory device. The following descriptions will focus on a conventional storage capacitor and a conventional method of forming the same.
FIG. 1
is a fragmentary cross sectional elevation view illustrative of a conventional storage capacitor provided in a semiconductor memory device. The semiconductor memory device is formed on a semiconductor substrate
101
such as a silicon substrate. Field oxide films
103
are selectively formed on a surface of the semiconductor substrate
101
, so that the field oxide films
103
define active regions or device regions. Gate insulation films not illustrated are provided on the active regions or the device regions of the semiconductor substrate
101
. Gate electrodes
102
are formed on the gate insulation films. A first inter-layer insulator
104
is provided which extends over the field oxide films
103
and the active regions or the device regions of the semiconductor substrate
101
. A second inter-layer insulator
105
is formed on the first inter-layer insulator
104
. A first level interconnection layer
106
extends through the second inter-layer insulator
105
. A silicon nitride layer
107
is provided on the second inter-layer insulator
105
. Contact holes are provided which penetrate the silicon nitride layer
107
, the second inter-layer insulator
105
and the first inter-layer insulator
104
to reach the surface of the semiconductor substrate
101
. First conductive films
111
are provided within the contact holes
110
, wherein the bottoms of the first conductive films
111
are in contact with the surface of the semiconductor substrate
101
. Second conductive films
115
are formed on the silicon nitride layer
107
, so that the second conductive films
115
are in contact with the tops of the first conductive films
111
within the contact holes
110
. A pair of the first conductive film
111
and the second conductive film
115
forms a bottom electrode
117
. A capacitive insulation film
118
is provided which extends on the second conductive film
115
. A top electrode
119
is provided which extends on the capacitive insulation film
118
. The bottom electrode
117
, the capacitive insulation film
118
and the top electrode
119
form a storage capacitor.
FIGS. 2A through 2L
are fragmentary cross sectional elevation views illustrative of semiconductor memory devices having storage capacitors in sequential steps involved in a conventional method of forming the semiconductor memory device.
With reference to
FIG. 2A
, field oxide films
103
are selectively formed on a surface of a semiconductor substrate
101
, so that the field oxide films
103
define active regions or device regions. Gate insulation films not illustrated are formed on the active regions or the device regions of the semiconductor substrate
101
. Gate electrodes
102
are formed on the gate insulation films. A first inter-layer insulator
104
is formed which extends over the field oxide films
103
and the active regions or the device regions of the semiconductor substrate
101
. A second inter-layer insulator
105
is formed on the first inter-layer insulator
104
. A first level interconnection layer
106
is formed which extends through the second inter-layer insulator
105
. A silicon nitride layer
107
is formed on the second inter-layer insulator
105
.
A photo-resist film is entirely applied on the silicon nitride layer
107
. The photo-resist film is patterned by a photo-lithography technique to form a first photo-resist pattern
108
on the silicon nitride layer
107
, wherein the first photo-resist pattern
108
has openings
109
at predetermined positions. The first and second inter-layer insulators
104
and
105
may be made of phospho silicate glass or boron phospho silicate glass. The first level interconnection layer
106
may be made of tungsten silicide.
With reference to
FIG. 2B
, the first resist-pattern
108
is used to carry out a first anisotropic etching process such as a dry etching process to form contact holes
110
which penetrate the silicon nitride layer
107
, the second inter-layer insulator
105
and the first inter-layer insulator
104
to reach the surface of the semiconductor substrate
101
.
With reference to
FIG. 2C
, the used first resist-pattern
108
is removed.
With reference to
FIG. 2D
, first conductive films
111
are formed within the contact holes
110
, wherein the bottoms of the first conductive films
111
are in contact with the surface of the semiconductor substrate
101
. The first conductive films
111
are made of polysilicon.
With reference to
FIG. 2E
, a first insulation film
113
is formed on the silicon nitride layer
107
and on the tops of the first conductive films
111
within the contact holes
110
. A photo-resist film is entirely applied on the first insulation film
113
. The photo-resist film is patterned by a photo-lithography technique to form a second photo-resist pattern
112
on the first insulation film
113
.
With reference to
FIG. 2F
, the second photo-resist pattern
112
is used to car out a second anisotropic etching process such as a dry etching process to selectively remove the first insulation film
113
to form mask patterns
114
on the silicon nitride layer
107
.
With reference to
FIG. 2G
, a second conductive film
115
is formed on the silicon nitride layer
107
and on the mask patterns
114
as well as on the tops of the first conductive films
111
within the contact holes
110
, so that the second conductive film
115
is in contact with the tops of the first conductive films
111
within the contact holes
110
.
With reference to
FIG. 2H
, a second insulation film
116
is formed on the second conductive film
115
.
With reference to
FIG. 2I
, the second insulation film
116
is subjected to an etch back until the second conductive film
115
over the mask patterns
114
are etched and the tops of the mask patterns
114
are made shown.
With reference to
FIG. 2J
, the mask patterns
114
and the second insulation films
116
are removed by etching process with use of the silicon nitride layer
107
as an etching stopper. As a result, a plurality of bottom electrodes
117
are formed, each of which comprises a pair of the second conductive film
115
and the first conductive films
111
.
With reference to
FIG. 2K
, a capacitive insulation film
118
is formed which extends on the second conductive film
115
and on the silicon nitride layer
107
.
With reference to
FIG. 2L
, a top electrode
119
is formed which extends on the capacitive insulation film
118
. As a result, a plurality of storage capacitors are formed, each of which comprises the bottom electrode
117
, the capacitive insulation film
118
and the top electrode
119
.
The above conventional storage capacitor and the conventional method of forming the same have the following disadvantages.
The bottom electrode
117
comprises two parts, for examples, the first and second conductive films
111
and
115
. There are necessary two processes for forming the first and second conductive films
111
and
115
respectively in order to form the bottom electrode
117
of the storage capacitor.
Further, a boundary between the first and second conductive films
111
and
115
is likely to be broken in cleaning process and pre-treatment process. Particularly, in the staked capacitor, a connecting area between the first and second conductive films
111
and
115
is very small and the connecting portion between the first and second conductive films
111
and
115
is likely to be broken. It was required how to prevent or avoid the connecting portion from b

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