Single-crystal – oriented-crystal – and epitaxy growth processes; – Forming from vapor or gaseous state – With decomposition of a precursor
Patent
1997-08-23
1999-03-16
Breneman, R. Bruce
Single-crystal, oriented-crystal, and epitaxy growth processes;
Forming from vapor or gaseous state
With decomposition of a precursor
117939, 117949, 117103, 438648, C30B 600
Patent
active
058823999
ABSTRACT:
The aluminum <111> crystal orientation content of an aluminum interconnect layer or the copper <111> crystal orientation content of a copper interconnect can be maintained at a consistently high value during the processing of an entire series of semiconductor substrates in a given process chamber. To provide the stable and consistent aluminum <111> content, or the stable and consistent copper <111> content, it is necessary that the barrier layer structure underlying the aluminum or the copper have a consistent crystal orientation throughout the processing of the entire series of substrates, as well. We have determined that to ensure the consistent crystal orientation content of the barrier layer structure, it is necessary to form the first layer of the barrier layer structure to have a minimal thickness of at least about 150 .ANG., to compensate for irregularities in the crystal orientation which may by present during the initial deposition of this layer. As an alternative to increasing the thickness of the first layer of the barrier layer structure, this first layer can be deposited a low process chamber pressure, so that harmful irregularities in the crystal orientation are eliminated.
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"Tin formed by evaporation as a diffusion barrier between Al and Si" (J. Vac. Sci Technol. 21 (1) May/Jun. 1982) Ting pp. 14-17.
Hogan Barry
Ngan Kenny King-Tai
Ramaswami Seshadri
Ahmed Shamim
Applied Materials Inc.
Breneman R. Bruce
Church Shirley L.
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