Method for the chlorination of a silicon compound

Organic compounds -- part of the class 532-570 series – Organic compounds – Silicon containing

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556477, C07F 708

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active

052585352

ABSTRACT:
A novel method is proposed for the chlorination of a silicon compound having, in a molecule, at least one hydrogen atom directly bonded to the silicon atom. The method comprises the step of reacting the starting silicon compound with anhydrous copper (II) chloride as a chlorinating agent in the presence of copper (I) iodide as a catalyst so as to substitute a chlorine atom for the silicon-bonded hydrogen atom. When the starting silicon compound has two or more of silicon-bonded hydrogen atoms, the chlorination reaction proceeds stepwise so that the inventive method provides a possibility of selective chlorination.

REFERENCES:
patent: 3231333 (1966-01-01), Jenkner
patent: 4053495 (1977-10-01), Deinhammer et al.
patent: 4665209 (1987-05-01), Corriu et al.
Chemical Abstracts, vol. 102 (1985), Abstract No. 178275f, Belyaev, V. N. et al., p. 769.

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