Method for increasing polysilicon grain size

Semiconductor device manufacturing: process – Coating of substrate containing semiconductor region or of... – Insulative material deposited upon semiconductive substrate

Reexamination Certificate

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C438S775000, C438S758000, C438S648000

Reexamination Certificate

active

07446056

ABSTRACT:
The present invention relates to a method for increasing the grain size of a polysilicon layer, which includes exposing a silicon oxide wafer in a deposition chamber to an amount, effective for the purpose, of nitrogen at a flow rate of at least about 240 standard liters per minute (slm). The instant invention further relates to a method for inhibiting the formation of a polysilicon seed in a furnace, which includes the treatment as noted above. The invention also relates to a method for forming a polysilicon layer, including: forming a silicon oxide layer on a substrate, the silicon oxide layer having a plurality of oxygen molecules therein; exposing the silicon oxide layer to a predetermined amount of nitrogen-containing gas in a furnace, whereby a plurality of nitrogen molecules in the nitrogen-containing gas replaces at least part of the oxygen molecules in the silicon oxide layer; and forming a polysilicon layer on the silicon oxide layer.

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Ted Kamins, “Deposition And Characteristics Of Polysilicon Films For Integrated-Circuit Applications”, Mat. Res. Co. Symp. Proc. vol. 106, 1988 Materials Research Society, pp. 3 through 14.
Thomas A. Carbone et al., “Correlation of Ellipsometric Volume Fraction to Polysilicon Grain Size from Transmission Electron Microscopy”, 1999 IEEE/SEMI Advanced Semiconductor Manufacturing Conference, pp. 359 through 367.

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