Method for improvement of electromigration of copper by carbon d

Semiconductor device manufacturing: process – Coating with electrically or thermally conductive material – To form ohmic contact to semiconductive material

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438584, 438597, 438687, H01L 214763

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active

061108170

ABSTRACT:
A method for forming a carbon doped copper layer, preferably an electrochemically deposited carbon doped copper layer over a semiconductor structure, comprising the following steps. A semiconductor structure having an upper surface is provided. The semiconductor structure is placed in an electrochemical bath having a predetermined concentration of carbon. A first carbon doped copper layer is electrochemically deposited for a first period of time at a first current density. The first carbon doped copper layer blanket fills the semiconductor structure and has a predetermined thickness and a first concentration of carbon. A second carbon doped copper layer is electrochemically deposited over the first carbon doped copper layer for a second period of time at a second current density. The second carbon doped copper layer has a predetermined thickness and a second concentration of carbon. The carbon doped copper layer formed by the process of the present invention has improved electromigration without causing high resistivity.

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patent: 5681779 (1997-10-01), Pasch et al.
patent: 5789320 (1998-08-01), Andricacos et al.
patent: 5872045 (1999-02-01), Lou et al.

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