Method for growth of crystals by pressure reduction of supercrit

Adhesive bonding and miscellaneous chemical manufacture – Delaminating processes adapted for specified product – Delaminating in preparation for post processing recycling step

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23295R, C30B 710

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active

045128464

ABSTRACT:
Crystals (51) of high morphological quality are grown by dissolution of a substance (28) to be grown into the crystal (51) in a suitable solvent (30) under high pressure, and by subsequent slow, time-controlled reduction of the pressure of the resulting solution (36). During the reduction of the pressure interchange of heat between the solution (36) and the environment is minimized by performing the pressure reduction either under isothermal or adiabatic conditions.

REFERENCES:
Phase Diagrams, vol. 3, 1970, Academic Press, Nielsen et al., pp. 36, 37, 40.
P. J. Shlichta and R. E. Knox, J. Crystal Growth, 3, 4 (1968), 808-813.
H. S. Booth and R. M. Bidwell, Chem. Rev., 44 (1949), 447-513.
V. J. Krukonis et al., "Supercritical Fluid Extraction of Plant Materials Containing Chemotherapeutic Drugs," manuscript paper presented at AIChE 87th National Meeting, Boston, MA, 1979.
R. J. Janssen-van Rosmalen and P. Bennema, J. Crystal Growth, 42 (1977), 224-227.
P. S. Chen, P. J. Shlichta, W. R. Wilcox and R. A. Lefever, J. Crystal Growth, 47 (1979), 43-60.
Abstract of Thesis, P. S. Chen, Ph.D., Chem. Eng. Dept., Univ. of Southern California (1977).
P. J. Shlichta, "Crystal Growth in a Spaceflight Environment," MPS Experiment #770100, Third Semi-Annual Report (Oct. 1979-Mar. 1980), Jet Propulsion Laboratory.
P. J. Shlichta, "Minimization of Convection during Crystal Growth from Solution," paper presented at the AACG Meeting, San Diego, CA, 7/25/81.
J. F. Kramer and W. A. Tiller, J. Chem. Phys., 37 (1962), 841.
R. F. Sekerta, ibid, 46 (1967), 2341-2351.
E. D. Kolb, J. C. Grenier and R. A. Laudise, "Solubility and Growth of AIPO.sub.4 in a Hydrothermal Solvent:HCl," J. Crystal Growth, 51 (1981), 178-182.

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