Method for forming a contact opening

Semiconductor device manufacturing: process – Making field effect device having pair of active regions... – Having insulated gate

Reexamination Certificate

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C438S399000, C438S637000, C438S639000, C438S666000, C438S671000, C438S672000, C438S770000, C438S787000, C438S948000, C438S950000

Reexamination Certificate

active

06808984

ABSTRACT:

BACKGROUND OF THE INVENTION
1. Field of the Invention
The present invention relates in general to a semiconductor process. In particular, the present invention relates to a method of using an image resist acting as a sacrificial layer for an inter-level dielectrics (ILD), and forming a contact opening in inter-level dielectrics (ILD) without etching.
2. Description of the Related Art
As ICs become more compact, semiconductor designs have reduced device dimensions. For example, the 64 M DRAM process has shifted from 0.35 &mgr;m to 0.3 &mgr;m or less, and the 128 M and 256 M DRAM process to less than 0.2 &mgr;m.
In the contact process of the array area of a memory unit, the transistor arranges with high density, so a self-aligned contact (SAC) process is typically employed to enhance precision and accuracy. First, the (boro-phosphosilicate glass (BPSG), tetracthoxysilane (TEOS) stacked layers, and the silicon oxide materials, are used to as an inter-level dielectrics (ILD, the insulator layer) covering the transistors, then a SAC bit line contact (CB holes) is formed in the insulator layer using an etching process, the polysilicon material is then filled into the bit line contact to serve as a bit line contact plug. Subsequently, a contact holes process is carried out in the array area which a gate electrode contact (CG holes) and a junction contact (CS contact) are formed in the above insulator layer. Next, the bit line conductive wire MO is etched to define the contact location of the bit line contact plug.
When the ILD is etched, the BPSG/TEOS insulator layer is etched through to expose junction area, exposing the silicon substrate to potential damaged, which results in a serious sub-threshold voltage (sub-Vt) problem, impacting the memory ability of the capacitor in the array area. Additionally, when the ILD is etched, the spacers on the sidewall of the gate electrodes (word line) are easily damaged, resulting in short circuits between word line and bit line. Moreover, when a semiconductor design has reduced device dimensions, the width between the gate electrodes is reduced, impeding the etching process, and resulting in open circuits.
FIGS.
1
~
2
show the conventional self-aligned contact fabrication resulting in bit line open circuits or word line/bit line short circuits.
Subsequently, in
FIG. 1
, the pad silicon nitride layer
28
, the BPSG layer
30
, and the TEOS
32
stacked insulator layer are formed on the silicon substrate
10
with the transistor structure, wherein the pad silicon nitride layer
28
is employed to prevent the B
+
/P
+
of the BPSG layer
30
diffusing to the silicon substrate
10
when a thermal process is performed, impacting the device characteristics. The transistor includes source
12
, drain
14
and gate structure
20
, the gate structure
20
includes gate oxide layer
21
, polysilicon layer
22
, tungsten silicon layer
23
, silicon nitride layer
24
and silicon nitride spacer
25
, on the sidewall of the gate structure
20
, wherein the gate electrode consists of the polysilicon layer
22
and the tungsten silicon layer
23
. Next, a resist layer
40
is formed on the TEOS layer
32
, with a contact opening pattern, then, using the resist layer
40
as a mask, the BPSG layer
30
/TEOS layer
32
is etched to form a contact opening
34
. Since the contact opening
34
widths of the exposed drain area
14
between the gate electrodes are less than 0.030 &mgr;m when the line width is minimized to about 0.09 &mgr;m, and, the BPSG layer
30
/TEOS layer
32
stacked insulator layer is very thick, the ILD is more difficult to etch when closer to drain area
14
, and once the etching reaction is complete, incomplete or unetched insulator residue
30
′ remains in the bottom of the contact opening
34
, preventing exposure of the drain area
14
. When the insulator residue
30
′ is not a conductor, the subsequently filled conductive material cannot be electrically connected, resulting in the described bit line contact open circuits.
In order to prevent open circuits, in
FIG. 2
, a conventional method uses overetching to etch the insulator residue
30
′ and the pad silicon nitride layer
28
, however, the etching selectivity of the silicon oxide material to the silicon nitride spacer is only around 10~15, and the silicon nitride layer
24
and the silicon nitride spacer
25
are easily removed, exposing the tungsten silicon
23
and polysilicon
22
of the gate electrodes, resulting in word-line/bit-line short circuits
Additionally, BPSG possesses excellent gap filling characteristics even if the line width is reduced to 0.09 or 0.07 &mgr;m; however, the width between the gate electrodes is minimized when the line width dimension is reduced, such that the gap between the gate electrodes is difficult to fill even with BPSG material, resulting in voids and leading to short circuits between the adjacent contacts of the individual bit lines. Different from
FIGS. 1 and 2
,
FIG. 3
shows that the two drains
14
are a portion of the transistor of the individual bit line. After etching the BPSG
30
and TEOS
32
stacked insulator layer to form a contact opening
34
using resist layer
40
as a mask, the resist layer
40
is then removed. Next, the contact opening
34
is filled with conductive material to form bit line contact plug
38
. Once the contact opening
34
forms void
36
, the conductive material is also filled into the void
36
, resulting in short circuits between contact plugs
38
of adjacent bit lines.
SUMMARY OF THE INVENTION
Accordingly, an object of the invention is to provide a method of forming a contact opening, and preventing the silicon substrate from damage during, for example, bit line contact etching.
Another object of the invention is to provide a method of forming a contact opening, and preventing the contact from open circuits due to narrow width between the gate electrodes.
Another object of the invention is to provide a method of forming a contact opening, and preventing word line/bit line from short circuits.
Another object of the invention is to provide a bit line contact process, and preventing contact plugs from short circuits due to the voids in the inter layer dielectric (ILD).
In order to achieve the above objects, the invention provides a method of forming a contact opening, comprising providing a substrate with transistors protected by a silicon-containing insulator layer, then, covering a non-silicon-containing resist layer on the substrate, with a level surface, next, covering a silicon-containing thin resist layer on the non-silicon-containing resist layer to form a stacked resist layer, with a level surface, patterning the stacked resist layer to form a resist stacked layer with a contact plug pattern overlying the doping areas, next, forming an insulator layer on the resist unmasked area using a selective deposition process, removing the stacked resist layer to expose the doping area, and forming a contact opening.


REFERENCES:
patent: 5565376 (1996-10-01), Lur et al.
patent: 6146940 (2000-11-01), Hong
patent: 6239011 (2001-05-01), Chen et al.
patent: 6524964 (2003-02-01), Yu
patent: 2003/0003756 (2003-01-01), Yu

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