Method for developing images in energy sensitive materials

Radiation imagery chemistry: process – composition – or product th – Imaging affecting physical property of radiation sensitive... – Forming nonplanar surface

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430325, 216 62, G03F 726

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active

060134186

ABSTRACT:
A lithographic process for device fabrication is disclosed in which a hydrogen fluoride vapor is used to develop a pattern from an image introduced into an energy sensitive resist material. A class of silicon-containing materials display excellent sensitivity in the ultraviolet and deep ultraviolet for the formation of patterns by radiation induced conversion into glassy compounds. When these materials are patternwise exposed to radiation in the presence of oxygen, the oxygen content of the unexposed region is significantly different from the oxygen content in the exposed region. The pattern is developed using HF because the higher oxygen content material is etched at a faster rate by HF than the lower oxygen content material. Materials are deposited from the vapor phase and show excellent promise for use as resists in the fabrication of electronic and optical devices.

REFERENCES:
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patent: 4921321 (1990-05-01), Weidman
patent: 5439780 (1995-08-01), Joshi et al.
patent: 5635338 (1997-06-01), Joshi
"Plasma-Deposited Organosilicon Thin Films as Dry Resists For Deep Ultraviolet", by Horn, M. W. et al., J. Vac. Sci. Technol. B 8(6), pp. 1493-1496, (Nov./Dec. 1990).
"Vapor Phoase SiO.sub.2 Etching and Metallic Contamination Removal in an Integrated Cluster System", by Ma, Y. et al., J. Sci. Technol., B 13(4), pp. 1460-1465, (Jul./Aug. 1995).
"Etching of Thermal Oxides in Low Pressure Anhydrous HF/CH.sub.3 OH Gas Mixture at Elevated Temperature", by Ruzyllo, J. et al., J. Electrochem. Soc. Vol. 140, No. 4, pp. L64-L66, (Apr. 1993).
"All Dry Lithography: Applications of Plasma Polymerized Methylsilane as a Single Layer Resist and Silicon Dioxide Precursor", by Weidman, T. W. et al., Journal of Photopolymer Science and Technology, vol. 8, No. 4, pp. 679-686, (1995).

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