Method for coating semiconductor surface, process for...

Semiconductor device manufacturing: process – Coating of substrate containing semiconductor region or of... – Multiple layers

Reexamination Certificate

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C438S763000, C438S689000

Reexamination Certificate

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07553775

ABSTRACT:
The present invention provides a method for coating a group4semiconductor surface composed mainly of a group4semiconductor elements and a process for producing group4semiconductor particles having a luminescent capability and semiconductor particles and a semiconductor element produced thereby. The method for coating a semiconductor surface according to the present invention comprises the steps of: providing a semiconductor material comprising a group4element selected from the group consisting of silicon, germanium, carbon, and tin; reacting the surface of the semiconductor material with an inert organic solvent-soluble and electron-donating reducing agent in the inert organic solvent to coat the surface of the semiconductor material with a metal derived from said reducing agent; and then reacting the surface of the semiconductor material with a compound with an electron withdrawing group, said compound comprising an element selected from the group consisting of group4elements and transition metal elements, to coat the surface of the semiconductor material with the group 4 element or the transition metal element derived from said compound with the electron withdrawing group. The utilization of this method can produce semiconductor particles or a semiconductor element such as a light emitting element and an optical modulator.

REFERENCES:
patent: 7288468 (2007-10-01), Jang et al.
patent: 2005/0070106 (2005-03-01), Kauzlarich et al.
Akira Watanabe, et al., “Soluble Three-Dimensional Polysilane with Organosilicon Nanocluster Structure”, Jpn. J. Appl. Phys., vol. 36, Sep. 15, 1997, pp. L 1265-L 1267.
James R. Heath, “A Liquid-Solution-Phase Synthesis of Crystalline Silicon”, Science, vol. 258, Nov. 13, 1992, pp. 1131-1133.
Richard K. Baldwin, et al., “Solution Reduction Synthesis of Surface Stabilized Silicon Nanoparticles”, Chem. Commun., 2002, pp. 1822-1823.

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