Energy-sensitive resist material and a process for device fabric

Radiation imagery chemistry: process – composition – or product th – Imaging affecting physical property of radiation sensitive... – Electron beam imaging

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430325, 4302701, 430913, 430945, G03C 500

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058436243

ABSTRACT:
The present invention is directed to a process for device fabrication and resist materials that are used in the process. The resist material contains a polymer that is the polymerization product of a monomer that contains alicyclic moieties and at least one other monomer. The polymer is formed by free radical polymerization, and the resulting polymer either has alicyclic moieties incorporated into the polymer backbone or pendant to the polymer backbone via saturated hydrocarbon linkages. Other monomers are selected for polymerization with the alicyclic moiety-containing monomer on the basis of the ability of the monomer to copolymerize by free radical polymerization. Although the polymers are contemplated as useful in resist materials that are sensitive to radiation in the ultraviolet, and x-ray wavelengths as well as sensitive to electron beam radiation, the polymers are particularly advantageous for use in process in which the exposing radiation is 193 nm, because the amount of ethylenic unsaturation in these resist materials is low.

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T.I. Wallow et al., Evaluation of Cycloolefin-Maleic Anhydride Alternating Copolymers as Single-Layer Photoresists for 193 nm Photolithography, Proceedings of the SPIE, vol. 2724, Mar. 11, 1996, pp. 355-364, XP002053109.
O. Nalamasu et al., "Revolutionary and Evolutionary Resist Design Concepts for 193 nm Lithography," Microelectronic Engineering, vol. 1, No. 35, Feb. 1997, pp. 133-136, XP004054025.
English translation of JP 1217453/2638887.

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