Edge bead removal for nanoporous dielectric silica coatings

Semiconductor device manufacturing: process – Coating of substrate containing semiconductor region or of... – Insulative material deposited upon semiconductive substrate

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438697, 438704, 438756, 438761, 438763, 438790, 216 91, 216 38, H01L 21469

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active

061402540

ABSTRACT:
A process for forming a nanoporous dielectric silica coating on a surface of a substrate. The process includes spin-depositing alkoxysilane composition onto a surface of a substrate; spin depositing a surface hydrophobizing agent or a solvent onto an edge portion of the substrate to thereby remove the alkoxysilane composition from that area; and then curing the alkoxysilane composition to form a nanoporous dielectric silica coating. In another embodiment, an alkoxysilane composition layer is deposited onto a surface of a substrate. Then a solvent for the alkoxysilane substantially removes a portion of the alkoxysilane layer on the edge portion of the surface. This results in a transfer or cascading of a quantity of the alkoxysilane from a region adjacent to the edge portion to form a relatively thinner layer of the alkoxysilane onto the edge portion of the substrate surface. Then the relatively thinner alkoxysilane layer is removed prior to curing the alkoxysilane.

REFERENCES:
patent: 4510176 (1985-04-01), Cuthbert et al.
patent: 4732785 (1988-03-01), Brewer
patent: 5955140 (1999-09-01), Smith et al.
patent: 6022812 (1999-09-01), Smith et al.

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